高压静电场对单板复合材料高机械性能的影响

Qian He, Tianyi Zhan, Zehui Ju, H. Zhang, Lu Hong, Zhiqiang Wang, N. Brosse, Xiaoning Lu
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引用次数: 3

摘要

将高压静电场(HVEF)作为一种新技术,通过提高受粘结强度直接影响的剪切破坏强度极限值,来获得高力学性能的单板层合材。研究了HVEF处理下木材的表面性能、PF的聚合程度、木材与PF的结合界面以及LVL的力学性能。结果表明,在HVEF处理下,由于极性基团(? ?)增加,自由基和总表面能增加。OH, ?CHO)和离子被触发,导致杨树和马尾松标本的接触角减小。HVEF在木材与uf之间的反应较多,在处理步骤中PF的交联反应较多。竖向密度曲线的变化趋势比对照更为陡峭,杨木和马松的最大密度分别增加了24.93%和30.24%,这是因为胶粘剂沿着黏结界面连续有序聚集,渗透深度减小到200 μ m左右,导致黏结抗剪强度提高,最终使黏结抗剪强度水平(?和?)的LVL力学性能增强。杨树LVL的弹性模量和静抗弯强度分别提高了14.65%、10.68%、20.67%和12.34%,马尾松LVL的弹性模量和静抗弯强度分别提高了17.30%、13.93%、18.55%和12.72%。杨树和马尾松的脱层率分别降低了49.57%和58.32%。
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Highly Mechanical Performance of Laminated Veneer Lumber Induced by High Voltage Electrostatic Field
The high voltage electrostatic field (HVEF), as a novel technology, was applied in the study to obtain a highly mechanical performance of LVL (laminated veneer lumber) by increasing limiting value of shear failure strength directly affected by bonding strength. The surface property of wood, polymerization extent of PF, bonding interface of wood-to-PF and mechanical properties of LVL were investigated under the HVEF treatment. The results showed that increased free radicals and total surface energy were acquired under the HVEF treatment resulting from more polar groups (?OH, ?CHO) and ions were triggered leading to decreased contact angles identified both for Poplar and Masson specimens. The HVEF provided more reactions among wood-to-UF and more cross linking reaction of PF occurred in the treating step. The tendency of vertical density profile was more extremely steep than the control with max density increased by 24.93% and 30.24% for Poplar and Masson LVL respectively since adhesive aggregated continuously and orderly along bonding interface and permeation depth reduced to around 200 ?m, accounting for improved bonding shear strength, which eventually brought an enhancement on mechanical properties of LVL with horizon shear strength (?and?), modulus of elasticity and static bending strength significantly enhanced by 14.65%, 10.68%, 20.67% and 12.34% for Poplar LVL and that of Masson LVL enhanced by 17.30%, 13.93%, 18.55% and 12.72%. Besides, the delamination ratio was decreased by 49.57% and 58.32% respectively both for Poplar and Masson specimens.
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