SТrategic煤与碳酸盐矿物原料热电联处理获得高效合成能源载体和非燃料产品的途径

A. V. Zhukov, A. V. Mikhalkov
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摘要

煤的气化和气体燃料的生产包括与燃料气的生产有关的三个主要方向:1)所产气体的组成和热容量;2)燃气发生器结构;3)获得的替代产品的特性-低CO含量和气体毒性,可以充分利用该气体用于家庭用途。在煤转化的工业过程中,最常用的组合技术是:固定灰半焦化+气化(低温焦炭);-半焦化+加氢液体产品(焦油);-气化+从生成的SYN气体合成高分子量碳氢化合物(СО+Н)(费托合成)。获取合成液体燃料的布置选择可根据具体条件、煤的成本和质量、能源供应、市场情况等进行。煤在气化和加氢过程中产生的产物对大气的污染比发电厂燃烧的煤少得多。在实施创新生产的组织和技术模式时,第一阶段包括以下矿物原料和新产品加工的组合方法:碳酸盐矿物原料加工:电石、二氧化碳(气态、液态或固态);2. 乙炔、植物生长调节剂(pgr)、植物保护产品(TAKAR)。第二阶段包括燃料产品和非燃料产品:合成乙醇(乙醇)、防冻剂、乙二醇、二氯乙烷、合成干燥油、丙酮等;2. 尿素、氨、气态和液态氮、甲醇、汽油等。
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SТRATEGIC APPROACHES OF COMBINED ELECTROTHERMAL PROCESSING OF COAL AND CARBONATE MINERAL RAW MATERIALS FOR OBTAINING OF HIGHLY EFFICIENT SYNTHETIC ENERGY CARRIERS AND NON-FUEL PRODUCTS
coal gasification and the production of gaseous fuels include three principal directionsrelated to the production of fuel gas: 1) composition and heat capacity of the produced gas; 2) gas generator structures; 3) characteristic properties of the obtained alternative product -low CO con-tent and gas toxicity, which allow making full use of this gas for domestic purposes. In industrial pro-cesses of coal conversion, the following combined technologies are used most often: — semi-cok-ing + gasification of fixed ash (low-temperature coke); — semi-coking + hydrogenation of liquid product (tar); — gasification + synthesis of high molecular weight hydrocarbons from the produced SYN gas (СО+Н) (Fischer-Tropsch synthesis). The choice of the layout for obtaining SLF (synthetic liquid fuel) can be based on specific conditions, the cost and quality of coal, energy supply, market conditions. The products obtained in the process of gasification and hydrogenation of coals pollute the atmosphere much less than the coal burned in electrical power plants. When implementing the organizational and technological model of innovative production, the first stage includes the following combined approaches for the processing of mineral raw materials and new products: 1. processing of carbonic mineral raw materials: calcium carbide, carbon dioxide (in a gaseous, liquid or solid state); 2. acetylene, plant growth regulators (PGRs), plant protection products (TAKAR).The second stage includes fuel and non-fuel products: 1. synthetic ethyl alcohol (ethanol), anti-freeze, ethylene glycol, dichloroethane, synthetic drying oils, acetone, etc .; 2. carbamide (urea), am-monia, nitrogen in gaseous and liquid states, methanol, gasoline, etc.
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