介孔硅铝酸盐是很有前途的石油化工催化剂载体

A. Abdrassilov, K. Abdildina, G. Vassilina, I. A. Klassen, N. Zabara, D. Baidulla
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引用次数: 0

摘要

目前,一些介孔材料及其性质的研究已经引起了一定的兴趣。介孔材料完全有可能成为工业非均相催化剂的组成部分。介孔硅铝酸盐催化剂在石油化工中广泛应用于加氢、重整、加氢异构、加氢裂化、加氢脱芳等反应。采用四乙基硅酸盐与仲氧化铝的共聚法制备了介孔硅酸铝(MAS)。十六烷基胺作为模板。采用氮吸附/脱附、x射线衍射、扫描电镜和TPDA等手段研究了合成的结构介孔硅酸铝及其双功能催化剂的理化性质。结果表明,所得样品具有有序的介孔结构,并具有必要的酸中心强度和浓度,可作为各种石化工艺双功能催化剂的酸组分。
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MESOPOROUS ALUMINOSILICATES AS PROMISING CARRIERS OF CATALYSTS FOR PETROCHEMICAL PROCESSES
Nowadays there is a number of research papers and a certain interest in some mesoporous materials and the study of their properties. Mesoporous materials have every chance to become components of industrial heterogeneous catalysts. Catalysts based on mesoporous aluminosilicates are widely used in the petrochemical industry for hydrogenation, reforming, hydroisomerization, hydrocracking, hydrodearomatization, etc. In this article mesoporous aluminosilicates (MAS) were synthesized by copolycondensation of tetraethylortosilicate and secondary aluminum butoxide. Hexadecylamine was used as a template. The physico-chemical characteristics of a synthesized structured mesoporous aluminosilicate and a bifunctional catalyst based on it were studied by nitrogen adsorption/desorption, X-ray diffraction, SEM and TPDA. It was found that the obtained samples have an ordered mesoporous structure and possess the necessary strength and concentration of acid centers for use as acid components of bifunctional catalysts of various petrochemical processes.
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