生物质基改性活性炭去除工业废水中的重金属

Hadiza Ado Suleiman, Salamatu Surajo Isah
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摘要

本研究以改性椰壳活性炭为前驱体,采用磷酸(h3po4)和氢氧化钠(Na O H)为浸渍剂,在600℃温度下,以Znlc 2为活化剂,对3种不同粒径的生物质进行热解碳化2小时,浸渍比为1:2的热加工工艺,对工业废水中的重金属铅(Pb)、铝(Al)、锰(Mn)、铁(Fe)和镉(Cd)进行脱除。椰壳的活性炭产率最高可达68g。确定了最佳活化温度、浸渍比、浸渍时间、吸附量和去除率。这项工作的结果表明,高质量的活性炭可以在当地从椰子壳废物中生产出来,而且这种生产的规模扩大将大大有助于减少该国椰子壳废物的产成量。
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The Removal of Heavy Metals from Industrial Effluents using Biomass Based Modified Activated Carbon
Modified coconut shell based activated carbon was used as a precursor in this study to remove heavy metals Lead (Pb), Aluminium (Al), Manganese (Mn), Iron (Fe), and Cadmium (Cd) from industrial effluent using the thermal process of pyrolysis and carbonization for 2 hr and impregnation ratio of 1:2 with phosphoric acid (H 3 PO 4 ) and sodium hydroxide( Na O H) for three different biomass particle size at 600 0 c temperature using Znlc 2 as an activating agent. A maximum activated carbon yield of 68g was obtained for the coconut shell. The optimum activation temperature, impregnation ratio, time, uptake capacity and removal rate were determined. The results of this work illustrates that high-quality activated carbon can be locally manufactured from coconut shell waste, and a scale-up of this production will go a long way in reducing the tons of coconut shell waste generation in the country.
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