复杂城市和工业城市的颗粒物来源分配:以西班牙塔拉戈纳为例

E. P. Sánchez, M. Sánchez-Guijarro, F. Sánchez-Soberón, J. Rovira, J. Sierra, M. Schuhmacher, M. Rosell, A. Soler
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引用次数: 3

摘要

在UltraPAR项目(评估密集工业活动地区环境细颗粒物和超细颗粒物的暴露和健康影响)的框架下,2016-2017年冬季监测了西班牙塔拉戈纳(加泰罗尼亚)12所学校的室外空气质量。配备石英过滤器的大容量空气采样器用于采样等于或小于10、2.5和1 μm的空气颗粒物(分别称为PM10、PM2.5和PM1)。这些环境样品连同一些源样品(海港、工业综合设施、焚化炉和道路交通)进行了化学、矿物学和同位素特征分析,预计将有助于评估不同排放源的贡献。初步结果表明,PM1、PM2.5和PM10的最大PM浓度分别为37 μg/m3、30 μg/m3和54 μg/m3,铅含量在10 ~ 13 ng/m3之间变化。通过x射线衍射(XRD)和扫描电镜(SEM)证实了海洋气溶胶对该沿海城市的影响。不同颗粒物大小的碳同位素特征可能是其来源(矿物与燃烧源)的潜在示踪剂。这些发现还与来自类似城市或该区域的其他研究的近期和较早的环境数据进行了比较,以探索其一致性和可能的时间变化。
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PARTICULATE MATTER SOURCE APPORTIONMENT IN COMPLEX URBAN AND INDUSTRIAL CITIES: THE CASE OF TARRAGONA, SPAIN
In the framework of UltraPAR project (Assessing the Exposure and the Health Effects of Ambient Fine and Ultrafine Particles in areas of intensive industrial activity) the outdoor air quality of 12 schools in Tarragona (Catalonia, Spain) was monitored in winter 2016–2017. High volume air samplers equipped with quartz filters were used for sampling airborne particulate matter equal or smaller than 10, 2.5, and 1 μm (known as PM10, PM2.5, and PM1 respectively). These ambient samples together with some sources samples (harbour, industrial complexes, incinerator and road traffic) were chemically, mineralogically, and isotopically characterized and it is expected to help assessing the contribution of different emission sources. Preliminary results show that the maximum PM concentrations reached 37 μg/m3 for PM1, 30 μg/m3 for PM2.5 and 54 μg/m3 for PM10 while the lead content varies in the range of 10 to 13 ng/m3. Through XRD and SEM the marine aerosol influence is confirmed in this coastal city. The carbon isotopic signatures of the different PM sizes could be a potential tracer of its origin (mineral vs combustion sources). These findings were also compared with recent and older environmental data from other studies in similar cities or specifically in this zone to explore its consistency and possible temporal variations.
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