用爆炸产生的超过热蒸汽气化气体、液体和固体废物

S. Frolov, V. A. Smetanyuk, I. A. Sadykov, A. S. Silantiev, I. O. Shamshin, V. S. Aksenov, K. A. Avdeev, F. Frolov
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摘要

采用脉冲爆轰枪技术对有机废物进行超高温蒸汽气化[1,2],首次进行了实验验证。有机废物转化器由脉冲爆轰枪和水冷球形低温反应器组成(图1)。进行了甲烷转化实验以及甲烷氧混合物高温气体爆轰产物对液体(废机油)和固体(锯末)废物的气化实验。脉冲爆轰枪在相对较低的频率f = 1 Hz下工作,在1200 K的水平下,在反应器内的时间平均绝对压力略高于P = 1 atm的情况下,提供了球形低温反应器内爆轰产物的时间平均平均温度。结果表明,该新技术可将甲烷完全(100%)转化为含H2和CO的合成气,H2/CO比值为≈1.25 2。液体和固体废物气化产生的合成气中,H2、CO和CH4的总含量分别为干基(体积)的80%和65%(体积)。产物合成气中对应的H2/CO比值分别为0.8和0.5。综上所述,甲烷转化实验以及液体和固体废气阳离子实验表明,在f = 1 Hz和P = 1 atm的相同条件下,合成气中H2和CO的组成几乎不依赖于原料类型(图2)。
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GASIFICATION OF GASEOUS, LIQUID, AND SOLID WASTES WITH DETONATION-BORN ULTRASUPERHEATED STEAM
The pulsed detonation gun technology for gasi¦cation of organic waste with ultrasuperheated steam [1, 2] has been demonstrated experimentally for the ¦rst time. The organic waste converter consisted of a pulsed detonation gun and water-cooled spherical §ow reactor (Fig. 1). Experiments on methane conversion as well as on the gasification of liquid (waste machine oil) and solid (sawdust) waste by the high-temperature gaseous detonation products of methane oxygen mixture were performed. The pulsed detonation gun was operated at a relatively low frequency of f = 1 Hz which provided a timeaveraged mean temperature of detonation products in a spherical §ow reactor at a level of 1200 K at a time-averaged absolute pressure in the reactor slightly higher than P = 1 atm. The novel technology was shown to provide complete (100%) conversion of methane into syngas containing H2 and CO with a ratio of H2/CO ≈ 1.25 2. Gasi¦cation of liquid and solid wastes led to the production of syngas containing reactive components H2, CO, and CH4 in the total amounts of 80 and 65 %(vol.) dry basis (d. b.), respectively. The corresponding H2/CO ratios in the product syngas were 0.8 and 0.5. Overall, experiments on methane conversion as well as liquid and solid waste gasi¦cation showed that under the same conditions at f = 1 Hz and P = 1 atm, the composition of syngas in terms of H2 and CO almost did not depend on the type of feedstock (Fig. 2).
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