利用香蕉皮去除水中Pb2+

Afrida Nurain, P. Sarker, Md. Shiblur Rahaman, Md. Mostafizur Rahman, Md Elias Uddin
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引用次数: 3

摘要

生物吸附法是一种方便的重金属修复方法。在本研究中,通过批量实验,研究了香蕉皮对水溶液中铅(Pb2+)的去除作用。利用傅里叶变换红外光谱(FTIR)对香蕉皮中的官能团进行了鉴定。采用Langmuir吸附等温线模型和Freundlich吸附等温线模型研究了吸附机理,并从Langmuir吸附等温线中确定了分离因子。研究了不同吸附剂用量、pH、Pb初始浓度、接触时间、温度和搅拌速度对干香蕉皮上Pb2+的吸附作用。吸附后,用原子吸收光谱(AAS)测定Pb2+。当吸附剂剂量为45 g L-1时,pH为5时吸附效果最佳。在25℃条件下,当初始Pb浓度为100 ppm时,最佳接触时间为30 min,搅拌速度为150 rpm。Langmuir和Freundlich吸附等温线模型对Pb2+的吸附均拟合最佳(r2 = 0.9978和0.9595)。Pb2+的最大吸附量为2.1 mg g-1。研究结果表明,香蕉皮废弃物可能是一种潜在的重金属去除吸附剂。此外,利用它去除废水中的Pb2+,可以以生态友好的方式解决废物管理问题。
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Utilization of Banana (Musa sapientum) Peel for Removal of Pb2+ from Aqueous Solution
Biosorption is a convenient process for heavy metal remediation. In this study, banana peel was experimented to eliminate lead (Pb2+) from an aqueous solution following batch experiments. The functional groups of banana peel were identified by Fourier-transform infrared spectroscopy (FTIR). The adsorption mechanism was studied by the Langmuir and Freundlich adsorption isotherm model and determined the separation factor from the Langmuir adsorption isotherm. The adsorption of Pb2+ on dried banana peel had been studied at different adsorbent doses, pH, initial concentration of Pb, contact time, temperature, and agitation speed. After adsorption, Pb2+ was measured using atomic absorption spectroscopy (AAS). Maximum adsorption had taken place at pH 5 for adsorbent dose 45 g L-1. The optimum contact time and agitation speed was 30 minutes and 150 rpm, respectively for the initial Pb concentration of 100 ppm at 25°C. Both, Langmuir and Freundlich adsorption isotherm models shows the best fitting (r2 = 0.9978 and 0.9595) for Pb2+ adsorption. The maximum Pb2+ adsorption capacity was 2.1 mg g-1. The findings indicate that the banana peel waste could be a potential adsorbent for heavy metal removal. Moreover, the waste management problem could be solved in an eco-friendly manner by utilizing it for the eradication of Pb2+ from wastewater.
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