铜和氧化铜纳米颗粒对Sn-4Zn合金瞬态蠕变性能的影响

Dr.Manal Maher
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摘要

Cu-Sn-Zn合金由于其无可比拟的优势,例如其极低的电阻率,高海拔商业强度和优良的焊接能力,在不同的制造应用中得到了广泛的应用。Sn-4Zn合金的解铅安排有利于相对最小的熔合度和最低的价格。然而,锌表现出较差的抗氧化性和耐腐蚀性,阻碍了焊接工作。本文研究了Cu和CuO纳米颗粒(NPS)的加入对Sn-4Zn合金瞬态蠕变性能的影响。研究了Sn-4Zn、Sn-4Zn-0.4 cuo (NPS)和Sn-4Zn-1.5 cu (NPS)三种Cu-Sn-Zn合金成分。利用x射线衍射仪(XRD)和扫描电子显微镜(SEM-EDX)对制备的合金样品进行微观组织表征。结果表明,添加0.4 CuO (NPS)可使Sn-4Zn合金的强度提高约11%,添加1.5 Cu (NPS)可使合金的延展性提高约14%。此外,Sn-4Zn的蠕变性能;研究了Sn-4Zn-0.4 CuO (NPS)和Sn-4Zn-1.5Cu合金在不同的加热温度下(从303到373 K的3度扩展)和10到24 MPa的7种不同的固定利用应力(σ)。结果表明,β和n的大小与蠕变试验环境(T)和应力(σ)有明显的联系,εtr = βtn。无论利用应力(σ)如何,系数(n)随T的升高而升高;而(β)则因生长(T)和/或应力(σ)而减小。(NPs)。
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Effect of Copper and Copper oxide Nanoparticles on The Transient Creep Properties of Sn-4Zn alloy
Cu-Sn-Zn alloys are excessively utilized in different manufacturing applications due to their unparalleled advantages, such as very its low resistivity, altitude business strength, and premium weld ability. Sn-4Zn alloy is concerning to the lead-liberation arrangement which is favourable in respect of the comparatively minimal fusion degree and minimal price. Nevertheless, Zn displays destitute oxidation and corrosion resistance which prevent welding employment. The present research studied the addition effect of Cu and CuO nanoparticles (NPS) on the transient creep properties of the Sn-4Zn alloy. Three compositions of Cu-Sn-Zn alloys were studied Sn-4Zn, Sn-4Zn-0.4CuO (NPS), and Sn-4Zn-1.5Cu (NPS). X-ray diffraction (XRD) and Scanning Electron Microscopy attached with Energy-dispersive X-ray spectroscopy (SEM-EDX) were used to investigate the microstructure of the prepared alloy samples. The results proved the addition of 0.4 CuO (NPS) to Sn-4Zn alloy increased the strength of the alloy by about 11%, while the addition of 1.5 Cu (NPS) increased the ductility of the alloy by about 14%. Additionally, the Creep property for Sn-4Zn; Sn-4Zn-0.4 CuO (NPS), and Sn-4Zn-1.5Cu alloys is investigated during distinct employing temperatures, three degrees extended between 303 until 373 K and under seven varied fixed utilized stresses (σ) from 10 MPa to 24 MPa. The results showed the magnitude of β and n is distinctly linked to the creep test circumstances (T) and stress (σ) as εtr = βtn. The coefficients (n) is raised by rising (T) regardless of the utilized stress (σ); while (β) is reduced by growing (T) and /or stress (σ). (NPs).
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