银基开关触点的成膜

S. Simko, A. Lee, S. Gaarenstroom, A. A. Dow, C. A. Wong
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引用次数: 4

摘要

大气污染物与银基开关触点材料的反应会产生腐蚀产物,从而对触点的电气性能产生不利影响。本研究将银基接触材料Ag/Cu/Ni、Ag/Ni和Ag/MgO/ ni3种材料置于含有SO/sub /、H/sub /S、NO/sub /和Cl/sub /的加速腐蚀环境中。同时也保持了高温和高湿。研究了电降解和腐蚀膜生长特性随暴露时间的变化规律。研究发现,接触电阻随着初始腐蚀膜的形成而迅速增大,加速老化环境下形成的主要腐蚀产物是氯化银和硫化银,腐蚀膜厚度和均匀性对接触电阻影响较大。
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Film formation on silver-based switching contacts
The reactions of atmospheric pollutants with silver-based switching contact materials produce corrosion products which can adversely affect the contact's electrical behavior. In the present study, three silver-based contact materials-Ag/Cu/Ni, Ag/Ni, and Ag/MgO/NiO-were exposed to an accelerated corrosion environment containing SO/sub 2/, H/sub 2/S, NO/sub 2/, and Cl/sub 2/. An elevated temperature and high humidity were also maintained. Both electrical degradation and corrosion film growth characteristics were studied as functions of exposure time. It was found that contact resistance increases rapidly with the initial corrosion film formation, silver chlorides and silver sulfides are the major corrosion products formed in the accelerated aging environment, and corrosion film thickness and uniformity have strong effects on contact resistance.<>
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