碳纳米管中氮掺杂浓度对质子交换膜燃料电池阴极性能的影响

W. Wong, W. R. Daud, A. Mohamad, A. Kadhum, K. Loh, E. Majlan
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引用次数: 0

摘要

氮掺杂碳纳米管电极被认为是质子交换膜燃料电池(PEMFC)的潜在催化剂。氮掺杂碳纳米管在燃料电池阴极电还原氧方面表现出了良好的性能。本文研究了碳纳米管中氮掺杂水平对氧还原的影响。利用循环伏安法研究了碳纳米管中氮掺杂程度与阴极活性之间的线性关系。表现出最高阴极活性的样品的特征是其表面有较高的结构缺陷,这些缺陷负责充当阴极氧还原反应的活性位点。
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Effect of nitrogen-doping concentration in carbon nanotubes on cathodic performance for proton exchange membrane fuel cell
Electrode fabricated by N-doped carbon nanotubes has been identified as a potential catalyst for proton exchange membrane fuel cell (PEMFC) application. N-doped carbon nanotubes have shown their ability in electro-reduction of oxygen at the fuel cell cathode. This paper presents a study on the effect of nitrogen-doping level in carbon nanotubes towards the reduction of oxygen. The half cell test studied using cyclic voltammetry analysis has shown a linear relationship between the nitrogen-doping degree in CNT and the cathodic activity. The sample which exhibited the highest cathodic activity was character by its higher structural defects on the surface that is responsible to serve as the active sites for cathodic oxygen reduction reaction.
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