高性能磁性制冷剂的发展及室温磁冷却的最新趋势

K. Fukamichi, A. Fujita
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引用次数: 0

摘要

从能源效率和环境安全的角度来看,开发新型高性能制冷剂是人们迫切需要的。近年来,我们开发了一种很有前途的磁性制冷剂化合物La(Fe1-xSix)13(0.86≤x≤0.90),它在应用磁场中表现出从顺磁态到铁磁态的一级流动电子变磁跃迁。通过调节La(fe1 - x6)13Hy中氢气的浓度,可以在室温下控制居里温度TC和冷却工作温度。此外,本发明化合物的导热性优良。还应该强调的是,目前化合物的元素非常便宜,经济实惠,对人体完全无害。
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Development of High-performance Magnetic Refrigerants and Recent Trend in Room-temperature Magnetic Cooling
The development of new high-performance refrigerants has been highly desired from the viewpoints of energy efficiency and environmental safety. Recently, we developed promising magnetic refrigerant compounds La(Fe1-xSix)13 (0.86≤x≤0.90), that show the first-order of itinerant-electron metamagnetic transition from the paramagnetic state to the ferromagnetic state in applied magnetic fields. By adjusting the hydrogen concentration in La(Fe1-xSix)13Hy, the Curie temperature TC and the working temperature for cooling are controlled covering room temperature. Furthermore, the thermal conductivity of the present compounds is excellent. It should also be emphasized that the elements of the present compounds are very cheap economically and completely harmless to humans.
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