粉末型有机填料生物基和合成石油基泡沫聚合物在长时间紫外线照射下的动态力学分析

M. A. Zulhakimie, UniversitiTun Hussein Onn Malaysia, Anika Zafiah M. Rus, N. Sulong, N. S. Salim
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摘要

木粉填料应用于生物基和环氧聚合物泡沫材料中,具有增强聚合物泡沫结构的潜力。本分析采用“莫兰蒂”木材填料类型作为填料。为了利用光学显微镜(OM)观察每个样品在不同时间紫外线照射下的孔径,我们进行了这项研究。本分析比较了不同填充率(0 wt%、5wt%、10 wt%、15wt%和20 wt%)的样品在不同紫外照射时间(0 ~ 6000小时,2000小时快速增加)下的力学性能。采用DMA Q800 TA装置对其力学性能进行了研究。为了获得其机械性能的产物,将尺寸为40 x 10 x 5 mm的样品夹入机器中。结果将显示从DMA测试得到的tan δ、损耗模量和存储模量的值。tanδ值表明,高掺量的填料会产生较高的tanδ值。与生物基聚合物泡沫相比,粉末填充的环氧聚合物泡沫具有最高的tan δ值。结果表明,tan δ值越低,填充率越高。随着聚合物泡沫中填充率的增加,其存储模量和损失模量的影响也随之增大。损耗模量和储存模量越大,温度越低。由于能量在紫外线照射下以热量的形式损失,高粉末填充比的生物基聚合物泡沫可以耗散更多的能量。
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Dynamic Mechanical Analysis of Bio-Based and Synthetic Petroleum Based Polymer Foams with Powder Type Organic Filler at Prolonged Ultra-Violet Exposure
Wood powder filler applied to the bio-based and epoxy polymer foams has the potential to reinforce the polymer foam structure. The 'Meranti' wood filler type was used as the filler in this analysis. In order to observe the pore size of each sample when exposed to different hours of UV exposure using optical microscopy (OM), this study was made.This analysis was conducted to compare the mechanical properties of each sample with different filler ratios of 0 wt%, 5 wt%, 10 wt%, 15wt% and 20 wt% at different UV exposure hours, which is 0 hour to 6000 hours with a 2000 hour rapid increase. Using the DMA Q800 TA unit, the mechanical properties were studied. In order to obtain the product of their mechanical properties, samples having a scale of 40 x 10 x 5 mm were clamped into the machine. The results will show the value of tan δ, loss modulus and storage modulus from the DMA test.The tan δ value shows that the high tanδvalue will be produced by the higher ratio filler. In contrast to bio-based polymer foams, epoxy polymer foams with powder fillers have the highest tan δ value. It shows that the higher filler ratio can be reported with the lower tan δ value. As the filler ratio filler in the polymer foams increased, the consequence of storage and loss modulus was found to increase. The greater the modulus of loss and the modulus of storage, the lower the temperature. As energy is lost as heat during UV irradiation exposure, bio-based polymer foams with a high powder filler ratio can dissipate more energy.
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