镍掺杂氧化铜纳米颗粒的合成、表征及光催化降解研究

Khurram Shahzad, Iqra Karim, Syed Mustansar Abbass, Hira Karim Hira Karim, S. Hussain, Muhammad Ashfaq, Mehrine Rehman
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引用次数: 2

摘要

摘要:本文研究了纯氧化铜纳米粒子和掺杂镍纳米粒子对有机染料的降解作用。采用共沉淀法合成了纯氧化铜纳米粒子和掺杂镍的氧化铜纳米粒子。氢氧化钠被用作沉淀剂。通过扫描电子显微镜(SEM)、漫反射显微镜(DRS)和紫外可见光谱对纳米颗粒进行了表征。SEM结果表明,所制备的颗粒均匀、规则、纯净、纳米级。DRS结果表明,氧化铜纳米粒子的带隙为3.37 eV,氧化镍纳米粒子的带隙为2.29 eV。镍掺杂后,铜氧化物的带隙由3.37 eV减小到2.39 eV。紫外光谱分析表明,光催化降解有机染料的效果随时间的延长而增强。镍掺杂氧化铜纳米颗粒具有优异的光催化降解能力。
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Synthesis, Characterization, and Photocatalytic Degradation of Nickel Doped Copper Oxide Nanoparticles
ABSTRACT:In the present study, the degradation of organic dyes was performed in the presence of pure and nickel doped copper oxide nanoparticles. In this co-precipitation method was used for the synthesis of pure and nickel doped copper oxide nanoparticles. Sodium hydroxide was used as a precipitating agent. These nanoparticles were characterized by scanning electron microscopy (SEM), diffuse reflectance microscopy (DRS), and Ultraviolet-Visible spectroscopy. SEM results showed that the prepared particles were uniform, regular, pure, and in nano-range. DRS result showed that the copper oxide nanoparticles had a bandgap of 3.37 eV while nickel oxide had a bandgap of 2.29 eV. After doping of Ni the bandgap of copper oxide decreases from 3.37 eV to 2.39 eV. UVVisspectroscopic analysis showed that the photocatalytic degradation of organic dyes increases with time. Nickel doped copper oxide nanoparticles have excellentphotocatalytic degradation ability.
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