PEMFC用双极板金属铝包覆碳的制备

P. Chinnasa, Wichaid Ponhan
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引用次数: 2

摘要

研究了用于质子交换膜燃料电池(PEMFC)系统的铝合金双极板的性能。采用喷涂方法对金属双极板进行涂碳改性。通过镀层结构、界面接触电阻(ICR)、腐蚀渗透速率(CPR)和单电池性能对铝合金双极板的性能进行了评价。通过对F、H、B、HB、2B、3B和4B型石墨棒选择条件下具有较低研磨阻力的混合导电涂料。本品是一种粘结剂,用于在涂层基材中分别添加3、6、9、12 wt%的条件下喷涂在铝板6061上。涂层在样品上的厚度和使用涂层的温度不同于研究样品的ICR和CPR。结果表明,4B型石墨棒具有较低的电阻。对6061铝板进行喷涂,喷涂系数为% 9 wt%石墨,喷涂50次,结果CPR为0.34348 mm/yr, ICR为87.67mΩcm2 a值较为合适。研究了温度对基片的影响,发现温度对基片的ICR很小,但基片的CPR能在高温下耐腐蚀,50℃时的CPR可达0.2636 mm/yr。这是制备双极板镀铝炭的适宜条件。研究了在质子交换膜(PEM)燃料电池中的应用,以产生绿色电能,证明了理论上的比电能存储。
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Fabrication bipolar plate metal aluminum coated carbon for PEMFC
The performance of Al-alloy bipolar plates for the PEMFC (proton exchange membrane fuel cell) system is investigated in this paper. The metallic bipolar plates are modified with coating carbon by spraying methods. The performance of the Al-alloy bipolar plates is evaluated by the coating structure, Interfacial contact resistance (ICR), corrosion penetration rate (CPR) and single cell performance. By the type graphite rods F, H, B, HB, 2B, 3B, and 4B Select conditions type graphite rods had lower resistance grinding mixed conductive paint. Used is a binder in coating Sprayed on the aluminum plate 6061 by had the condition in the coating substrate be 3, 6, 9 and 12 wt%. Thickness coating onto the sample and temperature using the coating different from studies ICR and CPR of the sample. The results showed factors graphite rods the type 4B had lower resistance. The aluminum plate 6061 through coating Sprayed at factor percent 9 wt% graphite the volume factor Sprayed 50 times have of results CPR 0.34348 mm/yr and results of ICR 87.67mΩcm2 a value is appropriate. The study of factors and of the temperature with substrate plate It was found that temperature to a substrate plate has very little ICR, but the results CPR of substrate can resistance corrosion at high temperatures and the temperature 50 °C have of results CPR 0.2636 mm/yr. Which are the proper conditions to apply for preparation bipolar plate metal aluminum coated carbon. The work studied the application in proton exchange membrane (PEM) fuel cells in order to generate green electric energy, demonstrating theoretical specific electric energy storage.
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