{"title":"现代水活性聚氨酯修复水工结构防水能力","authors":"O. Kovalenko","doi":"10.31073/mivg201901-155","DOIUrl":null,"url":null,"abstract":"The main material of the hydrotechnical structures of the water management and reclamation complex is concrete. Its durability is the main indicator of reliability of building operation. The high density of hydraulic concrete, which determines the water resistance, is a guarantee of its durability. At the same time, in hydraulic concrete during the operation under the influence of aggressive environmental factors various defects (cracks, dissected zones)develop, which reduce its waterproofing capability. These defectsare the main centers of water filtration through building structures. \nAt first, drip filtration develops in buildings, which in the course of time increases into active jet filtration. That can lead to the complete destruction of the building. In this connection, the issue of restoration of monolithicity and waterproofing of concrete hydro-technical constructions is relevant. The solution of the problem may be the use of injection waterproofing of the structures when using hydroactive polyurethane resins. Due to the presence in the chain of macromolecules the final isocyanate (-NCO) groups, polyurethanes are capable for interacting with water molecules with the release of carbon dioxide, which leads to foaming. As a result, water blockage occurs in the concrete body and its waterproofing is restored. \nThe analysis of the modern construction market shows that there is currently a sufficiently wide range of single- and two-component hydroactive polyurethane resins capable of reacting with water with foam formation. As the study has shown, the rate of polymerization, the beginning and the end of polyurethane compositionsfoaming substantially depend on the rate of catalyst or polymerization accelerator in the composition, as well as on the environmental temperature. So,when increasing the rate of catalyst in the mixture from 2 to 9%, the rate of polymerization reaction increases by 3,3-3,9 times, and when increasing the environmental temperature from 10 to 25 °C, the polymerization rate increases in 1,3-1,4 times. The foaming time of polyurethane compositions varies within 0,8 ... 16 minutes. Depending on the polyurethane formulations, the resins can be slow- reactive, fast-reactive and ultrafast-reactive, which opens a prospect for their application in the conditions of the filtration of different intensity: from drip to jet. \nTwo-component polyurethane resins are the most promising for application in the technology of injection waterproofing on hydraulic engineering structures of water management and reclamation area, which enable to eliminate water leakage through the structures of different intensity: from drip to active jet filtration. Two-component polyurethane resins such as CarboPur, Tunnelinjekt, PenePurFoam, when contacting with water, form a rigid elastic foam with high physical and mechanical properties: bending strength up to 80 MPa, adhesion to water-saturated concrete to 2, 8 MPa. \nField study proved the high efficiency of injecting waterproofing with the use of hydroactive polyurethane resins in the conditions of water filtration through the structures of docking facilities of pumping stations. In the course of implementation of the projects on the restoration of waterproofing of reinforced concrete structures, the following types of work were performed: eliminating leaks through the isolation joints of concrete, as well as through shrinkage and structural cracks; eliminating leaks in the adjacent zones of \"wall-floor\", \"wall-ceiling\"; sealing leaks through the places of engineering communications laying(pipelines); arrangement of shut-off and veal waterproofing in the walls (injection of resins into dilapidated zones of the structure).","PeriodicalId":298682,"journal":{"name":"Міжвідомчий тематичний науковий збірник \"Меліорація і водне господарство\"","volume":"216 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2019-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"MODERN HYDROACTIVE POLYURETHANE FOR RESTORATION OF WATERPROOFING CAPABILITY OF HYDROTECHNICAL STRUCTURES\",\"authors\":\"O. 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引用次数: 0

摘要

水利治理复垦综合体水工构筑物的主要材料是混凝土。其耐久性是衡量建筑运行可靠性的主要指标。水工混凝土的高密度决定了其抗水性,是其耐久性的保证。同时,水工混凝土在使用过程中受恶劣环境因素的影响,形成各种缺陷(裂缝、夹层),降低了其防水性能。这些缺陷是水通过建筑结构过滤的主要中心。起初,滴漏过滤在建筑物中发展,随着时间的推移,逐渐发展为主动射流过滤。这可能会导致整座建筑被彻底摧毁。在这方面,恢复混凝土水工工程的整体性和防水问题是相关的。该问题的解决方案可能是在使用水活性聚氨酯树脂时对结构进行注射防水。由于大分子链中存在最终的异氰酸酯(-NCO)基团,聚氨酯能够与水分子相互作用,释放二氧化碳,从而导致泡沫。从而使混凝土体发生水堵塞,恢复其防水性能。对现代建筑市场的分析表明,目前有足够广泛的单组分和双组分水活性聚氨酯树脂能够与水反应并形成泡沫。研究表明,聚合速率、聚氨酯组合物发泡的开始和结束在很大程度上取决于组合物中催化剂或聚合促进剂的用量以及环境温度。因此,当混合物中催化剂的用量从2%增加到9%时,聚合反应速率增加3,3-3,9倍,当环境温度从10℃增加到25℃时,聚合反应速率增加1,3-1,4倍。聚氨酯组合物的发泡时间在0,8…16分钟。根据不同的聚氨酯配方,树脂可分为慢反应性、快反应性和超快反应性,这为其在从滴滤到喷射过滤等不同强度的过滤条件下的应用开辟了前景。双组份聚氨酯树脂在水利管理和围垦区水利工程结构物的注入防水技术中最有应用前景,它可以通过不同强度的结构物(从滴漏到主动喷射过滤)来消除漏水。CarboPur、Tunnelinjekt、PenePurFoam等双组份聚氨酯树脂与水接触时,形成具有高物理机械性能的刚性弹性泡沫:抗弯强度可达80 MPa,与水饱和混凝土的附合力可达2.8 MPa。现场试验证明,在泵站对接设施结构过滤条件下,利用水性聚氨酯树脂注入防水具有较高的效率。在钢筋混凝土结构防水修复项目的实施过程中,进行了以下几类工作:通过混凝土的隔离缝,以及通过收缩和结构裂缝消除泄漏;消除“墙-地板”、“墙-天花板”相邻区域的渗漏;通过工程通信铺设(管道)场所封堵泄漏;在墙壁上布置关闭和小防水(在结构的破旧区域注入树脂)。
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MODERN HYDROACTIVE POLYURETHANE FOR RESTORATION OF WATERPROOFING CAPABILITY OF HYDROTECHNICAL STRUCTURES
The main material of the hydrotechnical structures of the water management and reclamation complex is concrete. Its durability is the main indicator of reliability of building operation. The high density of hydraulic concrete, which determines the water resistance, is a guarantee of its durability. At the same time, in hydraulic concrete during the operation under the influence of aggressive environmental factors various defects (cracks, dissected zones)develop, which reduce its waterproofing capability. These defectsare the main centers of water filtration through building structures. At first, drip filtration develops in buildings, which in the course of time increases into active jet filtration. That can lead to the complete destruction of the building. In this connection, the issue of restoration of monolithicity and waterproofing of concrete hydro-technical constructions is relevant. The solution of the problem may be the use of injection waterproofing of the structures when using hydroactive polyurethane resins. Due to the presence in the chain of macromolecules the final isocyanate (-NCO) groups, polyurethanes are capable for interacting with water molecules with the release of carbon dioxide, which leads to foaming. As a result, water blockage occurs in the concrete body and its waterproofing is restored. The analysis of the modern construction market shows that there is currently a sufficiently wide range of single- and two-component hydroactive polyurethane resins capable of reacting with water with foam formation. As the study has shown, the rate of polymerization, the beginning and the end of polyurethane compositionsfoaming substantially depend on the rate of catalyst or polymerization accelerator in the composition, as well as on the environmental temperature. So,when increasing the rate of catalyst in the mixture from 2 to 9%, the rate of polymerization reaction increases by 3,3-3,9 times, and when increasing the environmental temperature from 10 to 25 °C, the polymerization rate increases in 1,3-1,4 times. The foaming time of polyurethane compositions varies within 0,8 ... 16 minutes. Depending on the polyurethane formulations, the resins can be slow- reactive, fast-reactive and ultrafast-reactive, which opens a prospect for their application in the conditions of the filtration of different intensity: from drip to jet. Two-component polyurethane resins are the most promising for application in the technology of injection waterproofing on hydraulic engineering structures of water management and reclamation area, which enable to eliminate water leakage through the structures of different intensity: from drip to active jet filtration. Two-component polyurethane resins such as CarboPur, Tunnelinjekt, PenePurFoam, when contacting with water, form a rigid elastic foam with high physical and mechanical properties: bending strength up to 80 MPa, adhesion to water-saturated concrete to 2, 8 MPa. Field study proved the high efficiency of injecting waterproofing with the use of hydroactive polyurethane resins in the conditions of water filtration through the structures of docking facilities of pumping stations. In the course of implementation of the projects on the restoration of waterproofing of reinforced concrete structures, the following types of work were performed: eliminating leaks through the isolation joints of concrete, as well as through shrinkage and structural cracks; eliminating leaks in the adjacent zones of "wall-floor", "wall-ceiling"; sealing leaks through the places of engineering communications laying(pipelines); arrangement of shut-off and veal waterproofing in the walls (injection of resins into dilapidated zones of the structure).
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