微波氧等离子体改性PVA薄膜的ATR-FTIR和UV-vis光谱研究

S. Elashry, H. Elsaeed, N. El-siragy
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引用次数: 1

摘要

在本研究中,公开了一种基于微波炉的等离子体产生工艺,既简单又低成本。观察到一条类似帕斯琴的曲线。聚乙烯醇(PVA)聚合物具有优良的性能,经等离子体处理后可用于食品包装和农业等许多领域。采用溶液浇铸法制备了纯聚乙烯醇(PVA)薄膜。在第二种情况下,氧等离子体处理在1000W的恒定功率下,在不同的o2流量和压力下对PVA表面进行修饰。采用XRD、ATR-FTIR和UV-vis光谱对膜的表面性能进行了表征。x射线研究表明,纯PVA薄膜本质上是半结晶的。处理后的等离子膜在15秒、26毫巴和6升/分钟时透射峰明显增强。在26毫巴时,观察到轻微的峰移向更高的波数,对应于乙酰基的C-O拉伸。在与FTIR相同的优化条件下,紫外-可见光谱的紫外区透射率最高,接近64%。由于这些发现,PVA成为温室的透明材料。第二种方法的技术仍然有限。本工作旨在研究聚乙烯醇聚合物,以证明其在农业上的应用。透射比未经处理的
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ATR-FTIR and UV-vis spectroscopy studies of microwave oven-generated oxygen plasma modification for PVA films
In this study, a microwave oven-based plasma generation process is disclosed that is both easy and low-cost. A Paschen-like curve is observed. Because of polyvinyl alcohol (PVA) polymer's excellent properties, it can be used in many fields, including food packaging and agriculture, after plasma treatment. A solution-casting approach was used to create pure polyvinyl alcohol (PVA) film. In the second regime, Oxygen plasma treatment was used to modify the PVA surface at a constant power of 1000W with different O 2 flow rates and pressures. XRD, ATR-FTIR, and UV-vis spectra were used to examine the surface properties of the films. An X-ray study revealed that the pure PVA film is semi-crystalline in nature. The transmission peaks of the treated plasma film are clearly intense at 15 sec, 26 mbar, and 6 L/min. At 26 mbar, a slight peak shift towards higher wavenumbers is observed, corresponding to the C-O stretching of acetyl groups. The highest transmittance, nearly 64 percent, is found in the UV region of the UV-vis spectra at the same optimised conditions as FTIR. As a result of these findings, PVA became a transparent material for greenhouses. technique is still limited in the second regime. The present work aimed to study the PVA polymer to demonstrate its usage in agricultural applications. transmittance untreated
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