基于多层器件结构的互补色混合白色有机发光二极管

Aparna Tripathi, Pankaj Kumar
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摘要

白色有机发光二极管(WOLEDs)是一种新兴的发光技术,从液晶显示器的背光源到下一代显示器和固态照明都有许多应用。我们在此报道了有机发光二极管(oled)的制造,它通过多层彩色方法发出白光。这些WOLEDs结合了两种互补色的材料,发出绿蓝色和红橙色,形成白色。每一层发出的光的数量是这样选择的,两种发出的光混合在一起发出白光。每层的光发射量是通过选择最佳的每层厚度和在发射层之间加入薄孔阻挡层来控制的。对于绿蓝色光,我们使用了磷光掺杂剂FIrPic,而对于红橙色光,我们使用了磷光掺杂剂Ir(btp) 2 (acac),这两种掺杂剂都掺杂在宿主CBP中。我们研究了工作电压对这些WOLEDs发射光颜色的影响,发现发射光的颜色几乎与工作电压无关。WOLEDs在15 V下的辐射为1600 cd/ m2,国际照明委员会(CIE)坐标为(0.25,0.32)。我们还研究了这些器件的电流密度与电压(J-V)和电压与发光(V-L)特性,并计算了它们的效率,发现它们的效率为0.35 cd/A。为了演示目的,我们还准备了一些基于WOLEDs的数字显示器。
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White Organic Light Emitting Diodes Via Complementary Color Mixing Approach Through Multilayer Device Architecture
White organic light emitting diodes (WOLEDs) are emerging as potential light emitting technology and have found many applications from back light for liquid crystal displays to next generation displays and solid-state lighting. We report here the fabrication of organic light emitting diodes (OLEDs), which emit white light via multilayer color approach. These WOLEDs incorporated the materials emitting two complementary colors greenish-blue and reddish-orange to make white. The amount of light emitted from each layer was chosen in such a way that the mixture of the two emitted lights gave white light. The amount of light emitted from each layer was controlled by taking optimum thickness of each layer and incorporating a thin hole blocking layer of BCP in between the emissive layers. For greenish-blue light, we used a phosphorescent dopant FIrPic whereas for reddish-orange light we used the phosphorescent dopant Ir(btp) 2 (acac) and both of these dopants were doped in the host CBP. We studied the effect of operating voltage on the color of the emitted light of these WOLEDs and found that the color of the emitted light was almost independent of operating voltage. The WOLEDs emitted 1600 cd/m 2 at 15 V with Commission Internationale de I’Eclairage (CIE) coordinates (0.25, 0.32). We also studied the current density vs voltage ( J-V ) and voltage vs luminescence ( V-L ) characteristics of these devices and calculated their efficiency which was found to be 0.35 cd/A. We also prepared some WOLEDs based numeric displays just of the demonstration purpose.
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