二醇基助磨剂中添加硼化合物对水泥抗压强度的影响

Murat Çallı, E. Pehlivan
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引用次数: 0

摘要

研究了用二醇基助磨剂取代硼化合物对水泥抗压强度性能的影响。以单乙二醇(MEG)和二乙二醇(DEG)作为乙二醇基助磨剂,以无水硼砂和硼酸作为硼化合物进行试验。在硅酸盐熟料和石膏中加入助磨剂,进行了CEM I型水泥的生产试验。所有生产的水泥样品都进行了Blaine细度、xrf元素分析和2、7和28天抗压强度测试。磨助剂的测试结果表明,MEG和硼化合物混合物在任何年龄的抗压强度性能都没有增加与MEG使用本身有关。然而,在DEG中添加硼化合物提高了所有日龄(2、7和28日龄)的助磨性能。这种增加的可能原因可能是在碱性介质中与DEG和硼酸形成硼酸酯。
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Effects of Adding Boron Compounds to Glycol Based Grinding Aids on Cement Compressive Strengths Performance
In this study, the effect of substituting boron compounds with glycol-based grinding aids to the compressive strength performances of cement was investigated. Monoethylene glycol (MEG) and diethylene glycol (DEG) were used as glycol-based grinding aids, and anhydrous borax and boric acid were used as boron compounds in the tests. CEM I type cement production was carried out with the addition of grinding aid mixtures to Portland clinker and some gypsum in the experiments. All produced cement samples were tested for Blaine fineness, xrf elemental analysis and 2, 7 and 28 days compressive strength tests. Test results of grinding aids of MEG and boron compounds mixture showed no increase in any age of compressive strengths performances related to MEG used itself. However, with the addition of boron compounds to DEG increased grinding aid performance at all ages (2, 7 and 28 days). Possible reasons for this increase could be borate esters formed with DEG and boric acid in a basic medium.
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