不同气体和条件下衰弧非化学平衡效应的比较

Haonan Sun, Yi Wu, Yasunori Tanaka, K. Tomita, M. Rong
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摘要

本文比较了不同气体和不同条件下,衰减电弧的非化学平衡效应。研究了气体流量、电弧电流、压力和气体介质对非化学平衡行为的影响。通过增大电弧电流和喷嘴压力,可以减小非化学平衡效应。相反,增大气体流量会增强非化学平衡效应。此外,还研究了电弧在不同气体介质(空气、N2和O2)中的行为。由于在不同的气体介质中,反应过程会有很大的不同,即使气体介质的热力学性质和输运性质相似,电弧行为也会有很大的不同。因此,这里有一个非常重要的结论:在以前的工作中,通常认为热力学和输运性质将必然决定电弧的行为;实验结果表明,电弧等离子体中的过程和反应路径对电弧衰减阶段的电弧行为有重要影响。
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Comparison of Non-Chemical Equilibrium Effects in the Decaying Arc in Different Gases and Conditions
This paper compares non-chemical equilibrium effects in decaying arc in different gases and various conditions. The influences of the gas flow rate, the arc current, the pressure and the gas medium were investigated on the non-chemical equilibrium behavior. By increasing the arc current and the nozzle pressure, the non-chemical equilibrium effect will decrease. On the contrary, increasing gas flow rate enhances the non-chemical equilibrium effects. Additionally, the arc behaviors in different gas medium, which are air, N2 and O2 were investigated in this work. Since in different gas medium the reaction process will be quite different, even if the thermodynamic and transport properties of the gas medium are similar, the arc behaviors will be quite different. Therefore, here is a very important conclusion: in the previous works it was usually considered that the thermodynamic and transport properties will determine the arc behavior necessarily; the comparisons in this works clearly illustrate that the process and reaction path in the arc plasma will influence the arc behavior during the arc decaying phase dominantly.
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