合成环氧树脂(E)和生物环氧树脂聚合物泡沫与木材填料在紫外线照射下8000小时的动态力学分析

A. Alzomor, A. Z. M. Rus, H. A. Wahab, N. S. Salim
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引用次数: 0

摘要

聚氨酯(PU)材料最常见的可持续聚合物是使用可再生资源生产聚氨酯(PU)材料,这将减少对石油基产品消费的依赖。本文通过实验研究了合成环氧树脂(E)和生物环氧树脂(B)聚合物泡沫在0%、5%、10%、15%和20%的片状和粉末填充率下的动态力学和粘弹性性能,如存储模量(E′)、损耗模量(E′)和阻尼系数(tan δ)。然后将样品暴露在8000小时的紫外线照射下。在25-180°C的温度范围内,对(E)和(B)聚合物泡沫进行动态力学分析(DMA),频率为1hz。结果表明:掺有片状填料的20%合成环氧树脂,即填料配比最高的E20L试样,其存储模量和损耗模量值最大(分别为0.3125 MPa和0.0625 MPa),而其他填料配比下,由于泡沫与填料之间的粘结作用,合成环氧聚氨酯泡沫的粘度增大。添加5%粉末填充材料(B5P)的生物环氧聚氨酯泡沫具有最高的储能值(3956 MPa)和损耗模量(17213 MPa),表明生物环氧聚氨酯泡沫比合成环氧聚合物泡沫耗能更快。热重分析(TGA)表明,与生物环氧泡沫相比,合成环氧(E)聚合物泡沫具有更高的Tg值,E5L报告的Tg值最高(1.2),但由于多元醇结构不均匀,结果的可重复性较低。
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Dynamic Mechanical Analysis of Synthetic epoxy (E) and Bio-epoxy Polymer Foam Integrated with Wood Filler Under 8000 hours Exposure to UV Irradiation
The most common sustainable polymer for polyurethane (PU) materials is the production of polyurethane (PU) materials using renewable resources, which will reduce thedependency on petroleum-based products for consumption.This research presents findings from an experimental research on dynamic mechanical and viscoelastic properties such as storage module (E'), loss module(E") and damping coefficient(tan δ)of synthetic epoxy (E) and bio-epoxy (B) polymer foam with different loading ratios of 0%, 5%, 10%, 15% and 20% flakes and powder filler.The samples were then exposed to 8000 hours of UV irradiation. The samples were subjected to dynamic mechanical analysis (DMA) over a temperature range of 25-180 ° C for (E) and (B) polymer foam at a frequency of 1 Hz.The results showed that the 20 %synthetic epoxy with flakes filler material, namely as E20L sample with the highest filler ratio, gives the maximum storage module and loss module values (0.3125 MPa and0.0625 MPa respectively), among other filler ratios due to bonding between foam and filler resulting in increased viscosity of the synthetic-epoxy PU foam. The bio-epoxy PU foam with a 5% powder filler material (B5P), has the highest storage value (3,956 MPa) and loss module (17,213 MPa), showing that bio-epoxy PU foams can dissipate energy faster than synthetic-epoxy polymer foams.Thermogravimetric analysis (TGA) showed that the synthetic epoxy (E) polymer foam had a higher Tg value and the highest value was reported by E5L (1.2) compared to bio-epoxy foams with far less repeatable results due to the less homogeneous polyol structure.
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