扩大溶剂萃取在俄罗斯北极地区有色冶金废料和工业半成品处理中的应用及展望

A. M. Dvornikova, E. Shchelokova, A. Sokolov, A. Kasikov
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引用次数: 0

摘要

概述了俄罗斯北极铜镍工业引入溶剂萃取技术的历史。简要介绍了近年来工业废渣和半成品(如酸性废水、铁渣、冶金渣等)以及含稀有金属和铂类金属的废渣在SX领域的主要研究进展。特别提出了用脂肪醇基萃取剂从铜废电解液中回收硫酸SX的湿法-变态反应法,并进行了实验室规模试验。开发了用动力学改性(增效剂)羟基氧基萃取剂从废液中萃取铜和钯的通用电路等。结论是,在废物处理、获得额外有价值的产品和增加原材料加工的复杂性同时减少北极地区生态负荷方面,引入SX技术具有良好的前景。
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APPLICATION AND PROSPECTS FOR EXPANDING THE USE OF SOLVENT EXTRACTION IN THE PROCESSING OF WASTE AND INDUSTRIAL SEMI-PRODUCTS OF THE RUSSIAN ARCTIC ZONE NON-FERROUS METALLURGY
The overview briefly presents the history of solvent extraction (SX) technologies introduction at the Russian Arctic’s copper-nickel industry. The main developments of recent years in the field of SX of the in-dustrial wastes and semi-products such as acid substandard effluents, ferrous cakes, metallurgical slags, etc., as well as rare and platinum metals-containing waste, are also briefly shown. In particular, hydromet-allurgical method of sulfuric acid SX recovery from copper waste electrolyte with fatty alcohol-based extractant was proposed and laboratoryscale tested. General circuit for copper and palladium SX from waste solutions by kinetic-modified (synergist) hydroxyoxyme-based ex-tractant was developed, etc. It was concluded that there were favorable prospects for the introduction of SX technologies in the field of waste disposal, additional valuable products obtaining and increasing the complexity of raw materials processing while reducing the load on the ecology of the Arctic zone.
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