粉煤灰基支撑剂的穆斯堡尔和x射线荧光研究

A. Shokanov, A. Kyrykbayeva, B. Suleimenov
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摘要

本文讨论了用核磁共振波谱法(穆斯堡尔效应)和x射线荧光分析对国产铝土矿、高岭土、白粘土、沙子和粉煤灰等原料制备的支撑剂的研究结果。给出了支撑剂的超精细结构、电子态和元素组成。分析了热电厂Ekibastuz、Shubarkul、Karazhyralinsky煤粉燃烧过程中挥发性灰分的研究结果。根据研究结果,利用穆斯堡尔光谱和x射线荧光分析确定了支撑剂的各种复相组合和元素组成。在室温条件下,用57Co源在铬基体中以恒定加速模式在MS1104Em光谱仪上进行了穆斯堡尔测量。在岛津公司的EDX-7000装置上,使用能量色散x射线荧光光谱仪(RFS)测定了基于粉煤灰的支撑剂样品的元素组成。
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MOSSBAUER AND X-RAY FLUORESCENCE STUDIES OF FLY ASH BASED PROPPANTS
This article discusses the results of the study of proppants obtained from domestic raw materials - bauxite, kaolin and white clay, sand, as well as fly ash by nuclear gamma resonance spectroscopy (the Mossbauer effect) and X-ray fluorescence analysis. The hyperfine structure, electronic states and elemental composition of proppants are given. The results of the study of volatile ash obtained during pulverized coal burning of Ekibastuz, Shubarkul, Karazhyralinsky deposits at thermal power plants are analyzed. According to the results of the studies, various combinations of complex phases and the elemental composition of proppants were determined using Mossbauer spectroscopy and X-ray fluorescence analysis. The Mossbauer measurements were carried out on the MS1104Em spectrometer in the constant acceleration mode with a 57Co source in a chromium matrix at room temperature. The elemental composition of samples of proppants based on fly ash was determined using an energy dispersive X-ray fluorescence spectrometer (RFS) at the EDX-7000 installation of SHIMADZU.
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