聚苯胺填充GNPs纳米复合材料的电导率和天线性能

J. Razak, NorAisah Khalid, H. Hasib, M. A. Mahamood, MohdMuzafar Ismail, N. Mohamad, P. Puspitasari, M. H. Flaifel
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摘要

本研究旨在探讨导电聚合物纳米复合材料在柔性天线中的应用潜力。在酸性介质中,采用氧化苯胺聚合法制备了聚苯胺(PANI)填充石墨烯纳米片(GNPs)纳米复合材料。然后利用各种光谱和成像工具对聚苯胺/GNPs纳米复合材料进行了表征。发现聚苯胺大分子与GNPs片之间的强相互作用是由强?-?通过增加聚苯胺/GNPs纳米复合材料的Id/Ig比,验证了它们之间的共轭作用。结果,由于在更高的GNPs纳米填料负载(1.00 wt.%)下,电荷载流子输运量更大,PANI/GNPs纳米复合材料的电导率提高了三倍。随后,将聚苯胺/GNPs纳米复合材料粉末与橡胶涂料浆料结合,应用于棉织物上。报道了该天线的电导率、天线增益、回波损耗和辐射方向图。结果表明,与未填充的PANI相比,PANI/GNPs柔性纺织天线的恒定增益为4.1809 dB,回波损耗为-13.154 dB,辐射方向图工作在10.36 GHz,电导率提高100%。综上所述,利用聚苯胺/GNPs纳米复合材料在棉织物上作为柔性辐射贴片开发可穿戴纺织天线,在无线通信方面具有很大的潜力。
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Electrical Conductivity and Antenna Properties of Polyaniline filled GNPs Nanocomposites
This study was conducted to investigate the potential of utilizing conductive polymer nanocomposite for flexible type antenna application. The polyaniline (PANI) filled with graphene nanoplatelets (GNPs) nanocomposites were synthesized by an oxidative aniline polymerization in an acidic medium. The PANI/GNPs nanocomposites were then characterized by using various spectroscopy and imaging tools. It was found that the strong interaction between PANI macromolecules and GNPs flakes is caused by the strong ?-? conjugation between them, as validated by an increase of Id/Ig ratio of PANI/GNPs nanocomposites. As a result, it established a three-fold improvement for the electrical conductivity of PANI/GNPs nanocomposites, due to the larger amount of charge carrier transport at higher GNPs nanofiller loadings (1.00 wt.%). Later, the PANI/GNPs nanocomposites powder was applied to the cotton fabric by integrating it with a rubber paint slurry. Electrical conductivity, antenna gain, return loss, and radiation pattern of the antenna were reported. It was found that PANI/GNPs flexible textile antenna possessed a constant gain of 4.1809 dB, return loss at -13.154 dB, and radiation pattern which operated at 10.36 GHz for 100% improvement of electrical conductivity, in comparison with unfilled PANI. From these findings, it can be said that the development of wearable textile antenna utilizing PANI/GNPs nanocomposites on the cotton fabric as flexible radiation patch, has great potential for wireless communication purposes.
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