从电解质胶体中获得保护装饰性镍和锌涂层的电解质成分优化

L. Degtyar, M. Kolchina, E. Papina
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引用次数: 0

摘要

Box-Wilson的计划极限实验方法优化了镀镍和镀锌的电解质胶体的组成,以获得保护和装饰涂层。由此产生的低浓度镀镍电解胶体可以在与浓电流密度相同的电流密度下工作,在时间上更加稳定。在这种情况下,两种情况下的电沉积都是细晶的,有光泽的,耐腐蚀的。给出了电解镀锌胶体的最佳组成。在该组合物的电解质中,沉积有弹性的半锌涂层。目前锌的产量为76-80%。对镀镍和镀锌的电解质胶体进行了研究,揭示了这些溶液电沉积机理的一些特征。这为这些电解质在工业上的广泛应用开辟了前景。
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OPTIMIZATION OF COMPOSITIONS OF ELECTROLYTES FOR OBTAINING PROTECTIVE-DECORATIVE NICKEL AND ZINC COATINGS FROM ELECTROLYTE-COLLOIDS
The method of planning extreme experiments of Box-Wilson optimized the compositions of electrolytes-colloids of nickel plating and galvanizing for obtaining protective and decorative coatings. The resulting low-concentration electrolytecolloid of nickel plating makes it possible to work at the same current densities as the concentrated one, being more stable in time. In this case, the galvanic precipitation in both cases is fine-crystalline, shiny, and corrosion-resistant. The optimal composition of electrolyte-galvanizing colloid is shown. In the electrolyte of this composition, elastic, semi-zinc coatings are deposited. The current output of zinc was 76-80%. The conducted investigations of electrolytes-colloids of nickel-plating and galvanizing gave information about some features of the mechanism of electrodeposition from these solutions. This opens the prospect of a wider use of these electrolytes in industry.
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