反蛋白石光子晶体的制备及其拉曼增强特性

M. Ashurov, S. Klimonsky, A. Kavokin
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引用次数: 0

摘要

采用光固化树脂聚合法制备了基于乙氧基三甲基丙烷三丙烯酸酯(ETPTA)的反蛋白石光子晶体(PhCs)薄膜。将亚甲基蓝(MB)染料作为拉曼活性组分引入到反相PhCs孔中。在不同的光子停止带位置,记录了不同波长和入射角度下样品的拉曼光谱。在不含金纳米粒子和含金纳米粒子的反蛋白石样品中,发现了阻带对自发拉曼散射峰振幅的纯粹影响。
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Inverse Opal Photonic Crystals: Fabrication and Raman Enhancement Properties
Thin films of inverse opal photonic crystals (PhCs) based on ethoxylate trimethylolpropane triacrylate (ETPTA) were prepared from opal-type templates by photocurable resin polymerization. Methylene blue (MB) dye was introduced into pores of inverse PhCs as a Raman active component. Raman spectra were recorded at different wavelengths and angles of laser light incidence for samples with different positions of the photonic stop band. A pure effect of the stop band on the amplitude of spontaneous Raman scattering peaks were established for inverse opal samples without and with Au nanoparticles (NPs).
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