提高锂电池质量的研究进展

Peng Xiao
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摘要

金属锂具有良好的比容量和较低的还原电位,是目前最理想的电池正极材料之一。但是,仍然存在一些问题。例如,锂可能与电解质发生反应导致短路,其离子电导率可能达不到人们的预期,其枝晶和不稳定的电解质界面会产生安全问题,因此不能广泛应用。为了更好的利用电池的特性,避免电池的短缺,本文将根据四篇不同的文章介绍四种提高电池质量的方法。这四篇文章的主要思想是提出了一种用于卷曲锂阳极的特殊直立结构,展示了一种基于溶胶-凝胶的合成方法,该方法通过使用嵌段共聚物和均相聚合物作为额外的碳源来制造模板剂。生产固态聚合物电解质,与整个电池成分保持保形界面接触,并关注空气稳定的lixsiy保护层,使用基于溶液的方法在锂表面原位形成。通过提出各种新方法,我们可以找出它们之间的关系,并利用它们的优势来帮助探索更多的完整电池。因此,本文将为电池问题提供新颖有用的解决方案,让人们对锂金属电池有更多的了解。
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Research progress on improving the quality of lithium batteries
Lithium metal has good specific capacity and low reduction potential, and is one of the most favourable battery cathode materials. However, some problems still exist. For example, lithium may react with the electrolyte to cause short circuits, its ionic conductivity may not meet people's expectations, and its dendrite and unstable electrolyte interface will have security problems, so it can not be widely used. In order to make better use of the characteristics of the battery and avoid the shortages of the battery, this article will introduce four methods to improve the quality of the battery according to four different articles. The main ideas of the four articles are proposing a special upright structure using in the coiled Li anode, demonstrating a sol−gel based synthesis procedure that makes the templating agent by using a block copolymer and a homo-polymer as the extra carbon source, producing solid-state polymer electrolytes that keep conformal interfacial intercourse with the whole cell constituents and keeping an eye on the air-stable LixSiSy protection layer that using a solution-based method to form in situ on the face of the lithium. By proposing various new methods, we can find out the relationship between them and make good use of their advantages to help explore more whole batteries. Therefore, this paper will provide novel and useful solutions to battery problems, so that people can learn more about lithium metal batteries.
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