沸石和Fe-MOF对CO 2的吸附及碳捕集与封存

N. Daud, Nurul Huda Insyirah Mohammad Najib
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摘要

这项研究的重点是开发用于捕获和储存二氧化碳(CCS)的合适材料。制备了铁金属有机骨架(Fe-MOF)和沸石作为吸附剂进行CO2吸附。采用x射线衍射仪(XRD)和傅立叶变换红外光谱仪(FTIR)对吸附剂进行了表征。二氧化碳的吸附能力是在一个装配设备中进行的,该设备包含一个金属管状容器,该容器设置有来自圆柱形罐的纯二氧化碳气流。采用操作压力和吸附剂用量两种不同的参数,考察了两种吸附剂的性能。气相色谱法定期分析CO2出口浓度。FTIR和XRD分析结果表明,分子筛和Fe-MOF成功形成。两种吸附剂的最佳吸附条件为吸附剂剂量为0.3 g,操作压力为1 bar。综上所述,沸石具有比Fe-MOF更高的吸附能力,具有更好的CO2吸附剂性能。
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CO₂ Adsorption on Zeolites and Fe-MOF for Carbon Capture and Storage (CCS)
This research focused on the development of suitable materials for capturing and storing CO2 (CCS). Ferum-metal organic framework (Fe-MOF) and zeolite were prepared as adsorbents for the CO2 adsorption process. These adsorbents were characterised by employing X-ray diffraction (XRD) and Fourier Transform Infrared (FTIR) analysers. The adsorptive capacity of CO2 was conducted in an assembled facility containing of a metallic tubular container set up with a pure CO2 gas stream from a cylinder-shaped tank. The performance of these two adsorbents was investigated using two different parameters which are operating pressure and dosage of adsorbents. The exit concentration of CO2 was analyzed periodically using gas chromatography. Based on the FTIR and XRD studies, the findings suggest that the zeolite and Fe-MOF were successfully formed. The optimal adsorption conditions obtained for both adsorbents were 0.3 g of adsorbent dose and 1 bar of operating pressure. In conclusion, zeolite exhibits better performance as a CO2 adsorber due to its higher adsorption capacity than Fe-MOF.
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