辐射诱导的硅光导体和空间太阳能电池的两步降解

H. Amekura, N. Kishimoto, K. Kono
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引用次数: 11

摘要

由于在硅空间太阳能电池中发现了两步降解,即在低通量下逐渐降解和在高通量下急剧降解,因此进行了大量的研究以阐明其机理。最近的研究表明,这种急剧的降解是由散装过程引起的。提出了载流子迁移率降低或载流子耗尽的机制。独立于器件降解,我们观察到类似的两步降解体硅的光电性,并研究了相关现象。利用体积简单的优点,对陡坡降解机理进行了实验评价。因此,流动性变化的可能性被排除在外。虽然载流子耗尽同时发生,但光载流子寿命的迅速减少是显而易见的。用费米能级相关的深中心复合截面解释了寿命的下降。由于载流子耗竭引起费米能级跃迁,截面可能急剧增大。在本体降解的基础上,讨论了太阳能电池两步降解的起源。
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Radiation-induced two-step degradation of Si photoconductors and space solar cells
Since two-step degradation, i.e., gradual degradation at low fluence and steep at higher fluence, was found in Si space solar cells, extensive studies have been conducted to clarify the mechanism. Recent studies indicate that the steep degradation results from a bulk process. Either decrease in carrier mobility or carrier exhaustion has been proposed for the mechanism. Independently of the device degradation, we observed a similar two-step degradation in photoconductivity of bulk Si, and have investigated the relevant phenomena. Taking advantage of the bulk simplicity, the steep degradation mechanism has been experimentally evaluated. Consequently, a possibility of mobility change is excluded. A rapid decrease in photocarrier lifetime is evident, though the carrier exhaustion simultaneously occurs. The drop of lifetime is explained in terms of Fermi-level-dependent recombination cross-section of deep centers. As the Fermi-level jump is induced by the carrier exhaustion, the cross-section may steeply increase. The origin of two-step degradation in the solar cells is also discussed, based on the bulk degradation.
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