锂离子袋状电池集成光纤光栅传感器的长期稳定性研究

Johanna Unterkofler, R. Klambauer, Alexander Bergmann
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摘要

监测锂离子电池(LiB)的温度对其安全运行至关重要。锂离子电池的降解高度依赖于温度。将LiB保持在15°C到35°C之间的温度窗是理想的。否则,将加剧降解。到目前为止,只能测量LiB在单点的表面温度,但在运行过程中内部温度可能会显着更高。在这项工作中,我们将光纤布拉格光栅(FBG)温度传感器集成到锂离子袋电池中,并在四个月内评估了FBG传感器的灵敏度稳定性。两个袋状细胞的原型被制造出来,每一个都有两种纤维。每根光纤有三个fbg内嵌,因此每袋电池有六个温度测量点。FBG温度传感器包括具有三个内嵌FBG的聚酰亚胺涂层光纤和聚酰亚胺涂层熔融石英毛细管。由于毛细管的单侧安装点单一,光纤可以在毛细管中自由移动,减轻了外部应变对光纤光栅的影响。灵敏度每月测量一次,持续四个月。然而,布拉格波长随时间而变化,并且需要基线校正才能可靠地计算温度。测量结果显示灵敏度随时间的稳定性与其他出版物相当。
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Long-term stability study of fiber Bragg grating sensors integrated into a lithium-ion pouch cell
Monitoring the temperature of lithium-ion batteries (LiB) is crucial for safe operation. The degradation of a LiB is highly dependent on temperature. It is desirable to keep the LiB within a temperature window between 15 °C and 35 °C. Otherwise, enhanced degradation will take place. So far, only the surface temperature of a LiB at a single point is measured, but the internal temperature can be significantly higher during operation. In this work, we integrated fiber Bragg grating (FBG) temperature sensors into lithium-ion pouch cells and evaluated the stability of the sensitivity of the FBG sensors over four months. Two prototype pouch cells were manufactured each with two fibers. Each fiber has three FBGs inscribed, hence there are six temperature measurement points per pouch cell. The FBG temperature sensors comprise a polyimide-coated fiber with the three inscribed FBGs and a polyimide-coated fused silica capillary. The capillary mitigates the influence of external strain on the FBGs because the fiber can move freely in the capillary due to the single mounting point on one side of the capillary. The sensitivity was measured once a month for a period of four months. Although, the Bragg wavelength changed over time, and baseline correction is required for reliable temperature calculation. The measurements show comparable stability of sensitivity over time with another publication.
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