甲烷选择性氧化研究进展

S. Alshihri, H. Al-Megren
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引用次数: 4

摘要

甲烷的选择性氧化是催化学中最具挑战性的反应之一。甲烷是一种非常稳定的分子,需要高能量才能被激活。为了克服这一挑战,人们提出了不同的单步甲烷转化方法。然而,目前商业化的甲烷制甲醇的工艺是间接的,即甲烷首先在高密集的能量步骤中转化为合成气,然后合成气转化为甲醇。第一步负责工厂60%的资本成本。人们已经进行了大量的直接研究,并取得了一些良好的成果。本章将概述甲烷直接选择性氧化制甲醇的最新进展。
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Advances in Selective Oxidation of Methane
Selective oxidation of methane is one of the most challenging reactions in catalysis. Methane is a very stable molecule and requires high energy to be activated. Different approaches of single step methane conversion have been suggested to overcome this challenge. However, the current commercial process of methane conversion to methanol is via the indirect way, in which methane is first converted to synthesis gas in highly intensive energy step, and synthesis gas is then converted into methanol. The first step is responsible for 60% of the capital cost of the plant. There are enormous researches that have been conducted in a direct way and some good results have been achieved. This chapter will summarize the recent advances in the direct selective oxidation of methane to methanol.
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