椰壳活性炭化学活化工艺研究

E. Saputro, Varadilla Dwi Retno Wulan, Bellani Yunfa Winata, R. Yogaswara, N. K. Erliyanti
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引用次数: 5

摘要

碳或木炭可以由生物质或含有纤维素的材料制成,如椰子壳或蜡烛壳,使用热过程。热过程之一是热解,在这个过程中,物质转化为碳。热解的结果以三种产品的形式存在,即固体(木炭/碳),气体(燃料气体)和液体(生物油)。其他产物是气体,如二氧化碳(CO2)、甲烷(CH4)和一些含量较低的气体。一般来说,热解过程在300℃以上的温度下在4-7小时内发生。炭化碳或热解后由于孔隙结构不发育,吸附能力不大,需要活化处理。活化碳的一种方法是化学活化。有必要通过化学过程了解活性炭的最佳材料。本文旨在讨论各种类型的化学活化的优点和缺点,并确定有前途的化学活化。在各种化学活化方法中,最有希望制备活性炭的活化剂是磷酸(H3PO4),因为在<450℃的工作条件下,活化剂与样品的重量比约为29 - 52%,可以制备出微孔最大的活性炭。
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Process of Activated Carbon form Coconut Shells Through Chemical Activation
Carbon or charcoal can be made from biomass or cellulose-containing materials such as coconut shells or candlenut shells using a thermal process. One of the thermal process is pyrolysis, which in this process, the material is converted to carbon. The results of pyrolysis are in the form of three types of products namely solids (charcoal / carbon), gas (fuel gas) and liquid (bio-oil). Other products are gases such as carbon dioxide (CO2), methane (CH4) and some gases that have small contents. In general, the pyrolysis process takes place at temperatures above 300 ° C within 4-7 hours. Carbonized carbon or pyrolysis does not have a large adsorption capacity because the pore structure does not develop, so it is need activation process. One way to activate carbon is chemical activation. There is a need to know the best material for activating carbon through chemical process. This article aims to discuss the advantages and disadvantages of various types of chemical activation and to determine the promising chemical for activation. From various methods of chemical activation, the activator that promises to make activated carbon is Phosphoric Acid (H3PO4) because it can produce activated carbon which has a maximum micropore at operating conditions <450oC with a weight percent ratio between activator and sample around 29 - 52%.
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