MEH-PPV:I-MWCNTs纳米复合材料中碘掺杂多壁碳纳米管在有机太阳能电池中的应用

M. Sarah, F. Zahid, M. Eliás, U. Noor, M. Rusop
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摘要

本文讨论了碘掺杂多壁碳纳米管(I-MWCNTs)在MEH-PPV中不同组成比例对有机太阳能电池应用的影响。I-MWCNTs的组成从0、30、50、60和80 wt%不等,并研究了其对电学、光学和物理性能的影响。在将其混合到MEH-PPV溶液中之前,将MWCNTs掺杂碘受体原子。采用自旋镀膜技术将MEH-PPV:I-MWNTs纳米复合溶液沉积在玻璃和ITO衬底上。光电流随成分比的增加呈线性增加,光导率在60 wt%时达到最高值,为0.16 Ω/m。吸收系数约为9.7 × 105 m-1。因此,60 wt%用于制造有机太阳能电池,其效率约为0.0008%,Voc = 0.094 V, Jsc = 0.031 mA/cm2,填充系数= 0.269。
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Iodine doped multiwall carbon nanotubes in MEH-PPV:I-MWCNTs nanocomposite for organic solar cell applications
This paper discussed the effect of different composition ratio of Iodine doped multiwalled carbon nanotubes (I-MWCNTs) in MEH-PPV for organic solar cell applications. The I-MWCNTs compositions were varied from 0, 30, 50, 60 and 80 wt% and the effect to the electrical, optical and physical properties were investigated. The MWCNTs was doped with acceptor atoms which is Iodine, before it is being mix to the MEH-PPV solution. This nanocomposited MEH-PPV:I-MWNTs solution was deposited on glass and ITO substrates by spin coating technique. The photo-current showed linearly increased as the composition ratio increase, meanwhile the photoconductivity showed the highest value at 60 wt% with 0.16 Ω/m. This value is supported by the value of absorption coefficient which is around 9.7 × 105 m-1. Therefore, 60 wt% was used to fabricate organic solar cells, which gave efficiency around 0.0008%, Voc = 0.094 V, Jsc = 0.031 mA/cm2 and fill factor = 0.269.
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