铸造溶液法制备PVA-PAAm-Sb2O3纳米复合材料的分散参数

Baidaa Y. Mohemed, Sura. Alasdi, Sokina Fakfry, Khalid Haneen Abass, Ashraq Mohammed Kadim
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引用次数: 0

摘要

在这项研究中,研究了几种聚合物的光学和结构性质,以确定三氧化二锑Sb2O3的加入对它们的影响。通过在聚合物中加入不同浓度的Sb2O3,采用铸造工艺制备了几种薄膜。在200 ~ 1100nm范围内,对透射光谱和吸光度进行了分析。计算了间接允许跃迁的所有性质,包括吸收、消光、折射率、实介电常数和虚介电常数以及能隙。由于吸收系数小于104 cm-1,实验结果表明可以间接发生电子跃迁。随着Sb2O3浓度的增加,折射率和消光系数均增加。类似的能隙由陶克和温普尔-迪多梅尼科模型预测。
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Dispersion Parameters of PVA-PAAm-Sb2O3 Nanocomposites Prepared by Casting Solution Method
In this study, several optical and structural properties of polymers were investigated to determine how antimony trioxide Sb2O3 addition affected them. Several films have been produced for this purpose by adding Sb2O3 to polymers at varying concentrations using the casting procedure. Between 200 and 1100 nm, the transmittance and absorbance spectra were analyzed. All of the properties of the indirect allowed transition have been calculated, including its absorption, extinction, index of refraction, real and imaginary dielectric constants, and energy gap. Since the absorption coefficient was less than 104 cm-1, the experimental results indicated that electronic transitions could occur indirectly. Increasing the Sb2O3 concentration increased the index of refraction and extinction coefficient. Similar energy gaps were predicted by the Tauc and Wemple-DiDomenico models.
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