Lokesh Babu Jarugu, Yashwanth D. Vankar, Anita Brar
{"title":"α-羟基-β， γ-不饱和酯的合成","authors":"Lokesh Babu Jarugu, Yashwanth D. Vankar, Anita Brar","doi":"10.51611/iars.irj.v12i02.2022.212","DOIUrl":null,"url":null,"abstract":"α-hydroxy-β, γ-unsaturated esters are important building blocks of bioactive compounds, natural products, achiral and chiral vinyl epoxides. These could be easily obtained by isomerization of glycidic esters. In this paper we have reported easy and convenient way of synthesis of α-hydroxy-β, γ-unsaturated esters by isomerisation of glycidic esters using inexpensive catalyst HClO4-SiO2 and eco-friendly ionic liquid. Moderate to good yields with lower reaction times reported.","PeriodicalId":142446,"journal":{"name":"IARS' International Research Journal","volume":"37 1","pages":"0"},"PeriodicalIF":0.0000,"publicationDate":"2023-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"SYNTHESIS OF α- HYDROXY-β, γ-UNSATURATED ESTERS\",\"authors\":\"Lokesh Babu Jarugu, Yashwanth D. Vankar, Anita Brar\",\"doi\":\"10.51611/iars.irj.v12i02.2022.212\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"α-hydroxy-β, γ-unsaturated esters are important building blocks of bioactive compounds, natural products, achiral and chiral vinyl epoxides. These could be easily obtained by isomerization of glycidic esters. In this paper we have reported easy and convenient way of synthesis of α-hydroxy-β, γ-unsaturated esters by isomerisation of glycidic esters using inexpensive catalyst HClO4-SiO2 and eco-friendly ionic liquid. Moderate to good yields with lower reaction times reported.\",\"PeriodicalId\":142446,\"journal\":{\"name\":\"IARS' International Research Journal\",\"volume\":\"37 1\",\"pages\":\"0\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-05-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IARS' International Research Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.51611/iars.irj.v12i02.2022.212\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IARS' International Research Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.51611/iars.irj.v12i02.2022.212","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
α-hydroxy-β, γ-unsaturated esters are important building blocks of bioactive compounds, natural products, achiral and chiral vinyl epoxides. These could be easily obtained by isomerization of glycidic esters. In this paper we have reported easy and convenient way of synthesis of α-hydroxy-β, γ-unsaturated esters by isomerisation of glycidic esters using inexpensive catalyst HClO4-SiO2 and eco-friendly ionic liquid. Moderate to good yields with lower reaction times reported.
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