聚苯胺基纳米复合材料的电气应用研究进展

Farhad Ali, Shaista Noor, F. Ahmad, Shahbaz Nazir, Gulfam Nasar
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摘要

导电性聚苯胺(PANI)由于其高导电性、易合成性、高柔韧性、低成本和独特的氧化还原性能,在超级电容器、可充电电池和燃料电池等电化学能量存储和转换技术中得到了广泛的应用。由于其作为超级电容电极的稳定性较差,纯聚苯胺无法满足对更多n活性位点、更好的功率/能量密度和更稳定的分子结构的不断增长的需求。通过将聚苯胺与其他活性材料如碳化合物、金属化合物和其他导电聚合物(CPs)结合,可以克服作为超级电容电极的这些缺点。目前对聚苯胺的研究主要集中在聚苯胺改性复合电极和负载型复合电催化剂上,分别用于燃料电池和可充电电池。由于协同效应,具有各种独特结构的聚苯胺基复合材料在超级电容器、可充电电池和燃料电池中表现出优异的电化学性能。聚苯胺通常在不同的聚苯胺基复合结构中作为导电层和导电网络。本文还讨论了由聚苯胺制备的n掺杂碳材料,因为它们经常被用作燃料电池的无金属电催化剂。最后,我们对聚苯胺的发展趋势和未来的研究方向进行了简要的总结
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Pani-Based Nanocomposites for Electrical Applications: A Review
Including supercapacitors, rechargeable batteries, and fuel cells, conducting polyaniline (PANI) has been widely used in electrochemical energy storage and conversion technologies due to its high conductivity, ease of synthesis, high flexibility, low cost, and distinctive redox properties. Because of its poor stability as a super-capacitive electrode, pure PANI cannot keep up with the rising demands for more N-active sites, better power/energy densities, and more stable molecular structures. These drawbacks as a super-capacitive electrode can be overcome by combining PANI with other active materials such as carbon compounds, metal compounds, and other conducting polymers (CPs). Recent PANI research focuses mainly on PANI-modified composite electrodes and supported composite electrocatalysts for fuel cells and rechargeable batteries, respectively. Due to the synergistic effect, PANI-based composites with various unique structures have shown superior electrochemical performance in supercapacitors, rechargeable batteries, and fuel cells. PANI typically functions as a conductive layer and network in different PANI-based composite structures. This review also discusses N-doped carbon materials produced from PANI because they are frequently employed as metal-free electrocatalysts for fuel cells. We conclude by providing a quick summary of upcoming developments and future research directions in PANI
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