初生和再生聚丙烯共混物熔体流动指数修正的经验公式及共混物力学性能分析

L. G. Barbosa, Cassiano Rodrigo Dalberto, Edson Luiz Francesquetti
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摘要

聚丙烯因其易于加工和在不同用途下具有良好的力学性能而成为世界上使用最多的材料之一。因此,产生了大量聚丙烯废料,回收利用很重要。回收聚丙烯的问题是与原始聚丙烯相比,其性能发生了变化。回收这种材料后,可加工性参数和机械性能的牵引和冲击可以改变,影响到聚合物转化领域的公司。因此,本工作旨在得到一个修正原聚丙烯和再生聚丙烯混合物熔体流动指数的经验方程,并将其与原聚丙烯的力学性能进行比较研究。所得的经验方程表明,混合料的熔体流动指数与原聚丙烯的掺量呈线性关系。从力学性能来看,混合物的刚度与原聚丙烯相似,但在冲击下吸收的能量要低得多,这就影响了回收聚丙烯在这种应用中的使用。
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Obtaining an Empirical Equation for Correcting the Melt Flow Index of Virgin and Recycled Polypropylene Mixtures and Analysis of Mechanical Properties of the Blends
Polypropylene is one of the most used materials in the world because of its easy processability and good mechanical properties under different applications. As a result, a lot of polypropylene waste is being generated and recycling is important. The problem with recycling polypropylene is the changing in the properties when compared to virgin polypropylene. Processability parameters and mechanical properties of traction and impact can be changed after recycling this material, affecting companies in the polymer transformation sector. Thus, this work aims to obtain an empirical equation for the correction of the melt flow index of virgin and recycled polypropylene mixtures and also conducts a study on the mechanical properties of the mixtures comparing them with those of virgin polypropylene. The empirical equation found shows a linear relationship between the melt flow index of the mixture and the percentage amount of virgin polypropylene. From the mechanical properties, it was observed that the stiffness of the mixtures is similar to that of virgin polypropylene, however the energy absorbed under impact is considerably lower, compromising the use of recycled polypropylene for such application.
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