研究热压块铁的二次氧化速度,以预测其冶金价值保持时间

A. Timofeeva, T. V. Nikitchenko, A. Kozhukhov, N. Mazur
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引用次数: 1

摘要

热压块铁(HBI)和金属化球团一样,在运输和储存过程中会发生氧化。为了预测具有冶金值保留的HBI可接受贮存时间,有科学依据的型煤二次氧化速度数据是很重要的。国内外实践中有金属化球团二次氧化速度的测定方法,但实际科技文献中对HBI二次氧化问题的研究较少。为了确定HBI二次氧化速度,在A.A. Ugarov(国立研究技术大学“MISiS”分校)之后,Stary Oskol技术研究所冶金和金属科学系制定并测试了两种方法。第一种加权法是基于测定HBI在长期贮存过程中金属铁含量变化的方法。试验期间,每个月每12 h称重一次。实验测定的金属铁含量与化学分析的测定结果相差不到1%。加权法可以在没有特别费用的情况下获得HBI反应能力值,但需要进行足够长时间的实验,直到所研究的样品完全去除水分。另一种方法。密闭容器中蜂窝煤吸氧速度的测定。它可以在相对较短的时间内确定还原铁的反应能力,使压块测试具有足够的可靠性。在此基础上,阐述了满足实际生产要求的HBI二次氧化速度的测定方法。在装卸过程中,煤块会部分损毁。不同尺寸的成形碎片发生较高程度的氧化,降低了HBI冶金值。鉴于此,HBI氧化速度的研究继续根据不同的尺寸含量和确定HBI二次氧化速度的方法。
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Study of hot briquetted iron secondary oxidation speed aimed at forecasting of its metallurgical value retention duration
Hot briquetted iron (HBI), as also metallized pellets, undergo oxidation during transportation and storing. To forecast acceptable duration of HBI storing with metallurgical value retention it is important to have scientifically based data on the briquettes secondary oxidation speed. Methods of determining metallized pellets secondary oxidation speed are presented in domestic and foreign practice, but the matter of HBI secondary oxidation in scientific and technicalliterature practically is not covered. To determine HBI secondary oxidation speed two methods elaborated and tested at the Department of metallurgy and metal science of Stary Oskol Technological Institute after A.A. Ugarov (branch of National Research Technological University “MISiS”). The first– weighting method – based on determining of metal iron content change in HBI during a long term storing. During the experiment the mass of each briquette was weighted every 12 h within a month. The result of metal iron content determining by the experiment and by a chemical analysis had a difference of less than 1%. The weighting method enables to obtain the HBI reaction ability values without particular expenses, but requires carrying out long term enough experiments untilcomplete moisture removal out of the studied samples. The other method – determination of oxygen absorption speed bybriquettes in a closed vessel. It enables determining the reaction ability of the reduced iron within a comparatively short period, enables sufficient reliability duringthe briquettes testing. Based on it a methodology elaborated for determining of HBI secondary oxidation speed, meeting the requirements of real production. During loading-unloading operations, briquettes can partially go to ruin. The forming fragments of different sizes undergo a higher degree of oxidation that decreases the HBI metallurgical value. In view of this, studies of HBI oxidation speed continue depending on different sizes content and finalization of the methodology of determination of HBI secondary oxidation speed.
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