金属表面光聚合的研究

Suchitra Subrahmanyan, Fang Chen, H. Lackritz
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引用次数: 0

摘要

表面二次谐波发生用于研究乙烯基单体在金属表面光聚合过程中的表面反应。光聚合在制造无缺陷绝缘和耐磨涂层以及微电子器件方面显示出前景。尽管研究人员已经对气相反应进行了一些详细的研究,但对表面反应却知之甚少。此外,各种物理参数(如单体压力、光强、金属和单体的性质)对聚合物薄膜物理性能的影响尚不清楚。
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Studies of Photopolymerization at Metal Surfaces
Surface second harmonic generation is used to study surface reactions during photopolymerization of vinyl monomers on metal surfaces. Photopolymerization shows promise in making defect-free insulating and abrasion resistant coatings, and in the fabrication of microelectronic devices1. Although researchers have studied the gas phase reaction in some detail, little is known about the surface reactions2. Also, the effects of various physical parameters such as monomer pressure, light intensity, and the nature of metal and the monomer on the physical properties of polymer films are not known.
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