Yb3+共掺Pr3+:YAG激光晶体的光谱学

A. Lupei, V. Lupei, A. Petraru
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引用次数: 1

摘要

近年来,为了提高红外(二极管激光器)泵浦固体激光器的激发效率,大量地使用了其它稀土离子发射的Yb3+敏化。它是一种很好的Pr3+发射敏化剂。本文用光谱研究方法阐明了YAG中Pr3+的多位点结构性质和Yb3+在Pr3+:YAG上共掺杂的性质。在Pr3+:YAG中观察到两种类型的多位点:由非化学计量缺陷扰动的Pr3+位点和强耦合的Pr3+ - Pr3+近邻对。在Yb3+、Pr3+:YAG中的Pr3+谱线显示出新的谱线分配给邻近的Pr3+ - Yb3+对和Pr3+ - Yb3+ - Yb3+三元组。
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Spectroscopy of Yb3+codoped Pr3+:YAG laser crystals
The sensitization with Yb3+ of other rare earth ions emission is intensively used in the last years for increasing excitation efficiency of infrared (diode laser) pumped solid state lasers. It proved as a good sensitizer for Pr3+ emission in various matrices. The spectral investigations for the elucidation of the nature of multisite structure of Pr3+ in YAG and of the Yb3+ co-doping on Pr3+:YAG are presented in this paper. In Pr3+:YAG two types of multisites have been observed: perturbed Pr3+ sites by nonstoichiometric defects and strongly coupled Pr3+ - Pr3+ near neighbor pairs. Pr3+ spectra in Yb3+, Pr3+:YAG show new lines assigned to near neighbor Pr3+ - Yb3+ pairs and Pr3+ - Yb3+ - Yb3+ triads.
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