杜鹃(Lansium domesticum)果皮烃类的研究与表征

Erni Salasia Fitri, Redo Ardiansyah
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摘要

采用水热碳化法,在加热时间为8、10、12、24小时,温度变化为200、250℃的条件下,将杜姑果皮制备成碳氢化合物。通过x射线衍射(XRD)、傅里叶变换红外(FT-IR)、布鲁诺尔埃米特勒(BET)和扫描电镜(SEM)分析,确定了吸附剂在什么时间和温度变化下具有最佳的吸附质量。根据吸附剂的特性可以看出,最佳的加氢时间为12小时,温度为200℃。x射线衍射(XRD)分析表明,在15.7°和22.79°角处存在衍射峰,傅里叶红外(FT-IR)分析表明,振动峰有-OH, -CH, =CH, C=O, C=C芳族和脂肪族。Brunauer Emmet Teller (BET)分析可以看出,在200°C时,杜库果皮(Lansium domesticum)和水合物的表面积从12.343 m2 /g增加到22.635 m2 /g。扫描电镜(SEM)分析表明,大枣果(Lansium domesticum)材料的表面果皮具有同相的块状表面形态或称为聚集,而碳氢化合物往往具有不规则形状或可称为非均相形态。
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Study and Characterization of Hydrochar from Duku (Lansium domesticum) Peel
Peel of duku fruit (Lansium domesticum) was prepared into hydrochar by using hydrothermal carbonation method at heating time variation of 8, 10, 12, 24 hours and temperature variation of 200 and 250°C. X-Ray Diffraction (XRD), Fourier Transform Infra Red (FT-IR), Brunauer Emmet Teller (BET) and Scanning Electron Microscope (SEM) analyses were conducted to determine at what time and temperature variations the adsorbent had the best adsorption quality. Based on the characteristics of the adsorbent, it can be seen that the best hydrochar is at 12 hours and at a temperature of 200°C. X-Ray Diffraction (XRD) analysis showed the presence of diffraction peaks at angles of 15.7° and 22.79° Fourier Transform Infra Red (FT-IR) analysis obtained explained that there were peaks of vibration peaks namely -OH, -CH, =CH, C=O, C=C aromatic and aliphatic. Brunauer Emmet Teller (BET) analysis can be seen that the increase in surface area on duku fruit peel (Lansium domesticum) and hydrochar at 200°C from 12.343 m2 /g to 22.635 m2 /g. Scanning Electron Microscope (SEM) analysis shows that the surface peel of duku fruit (Lansium domesticum) material has a clumped surface morphology in the same phase or also called aggregation, while the hydrochar tends to have an irregular shape or can be called heterogeneous morphology.
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