硅薄膜太阳能电池用硅层定向再结晶

C. Hebling, S. Reber, K. Schmidt, R. Ludemann, F. Lutz
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引用次数: 14

摘要

采用区域熔炼加热器(ZMH)对不同封装陶瓷和石墨衬底上的硅薄层进行定向再结晶。采用等离子体增强化学气相沉积(PECVD)技术制备了高质量的SiO/ sub2 /和SiN/ subx /层。研究了SiO/sub - 2/和SiN/sub - x/层体系的机械稳定性,以及电活性杂质通过这些层向衬底外扩散的情况。采用垂直于扫描方向安装卤素灯的新设计的可移动大面积加热器(LAH),对覆盖有多孔SiO/sub - 2/中间层的各种mc- Si和带状Si衬底上沉积的薄Si层进行再结晶。提出了一种自动检测熔点的算法,并在这些播种孔外实现了均匀再结晶。
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Oriented recrystallization of silicon layers for silicon thin-film solar cells
A zone melting heater (ZMH) was used for oriented recrystallization of thin Si layers which were deposited on different encapsulated ceramic as well as on graphite substrates. The encapsulation consisted of high quality SiO/sub 2/ and SiN/sub x/ layers deposited by plasma enhanced chemical vapor deposition (PECVD). The mechanical stability of such SiO/sub 2/ and SiN/sub x/ layer systems as well as the diffusion of electrically active impurities out of the substrate through these layers were investigated. A newly designed moveable large area heater (LAH) with halogen lamps mounted perpendicular to the scanning direction was used to recrystallize thin Si layers deposited on various mc- and ribbon-Si substrates covered with perforated SiO/sub 2/ intermediate layers. An algorithm to detect the melting point automatically was developed and homogeneous recrystallization out of these seeding holes could be achieved.
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