微乳液法合成钙取代钴锌铁氧体及其表征

Zeshan Mehboob, M. S. Shifa, Humaira Akhtar Shahia, Muhammad Hashim
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摘要

钴锌铁氧体具有强磁致伸缩、高耐蚀性和优异的化学稳定性。通过改变Co-Zn铁氧体的颗粒分布和粒径,可以控制其铁磁性和顺磁性。钴锌铁氧体的合成方法有共沉淀法、溶胶-凝胶法和自燃法等。在本研究中,我们将采用微乳液技术合成Co-Zn铁氧体,并用不同的成分代替Ca。XRD结果表明,样品为单相铁氧体。粒径在34 ~ 14nm之间。平均晶格常数为8.11 ~ 8.18 ao。FT-IR与XRD分析结果一致。扫描电镜显示了样品的形貌和晶粒尺寸。随着Co0.6-x-Zn0.CaxFe2O4中Ca浓度的增加,晶粒尺寸减小。TGA结果与文献一致
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Synthesize and Characterization of Ca Substituted Co-Zn Ferrites by Micro-Emulsion Technique
Co-Zn ferrites have great magneto-striction, high corrosion resistivity and excellent chemical stability. We can control the ferromagnetic properties and paramagnetic properties of Co-Zn ferrites by changing its particle distribution and particle size. There are different types of techniques are available to synthesis Co-Zn ferrites like co-precipitation, sol gel and auto-combustion method etc. In this research, we will synthesize Co-Zn ferrites by micro-emulsion technique and substitute Ca in it with different composition. XRD results showed that samples were in single phase ferrite. Particle size was between the ranges of 34-14nm. Average lattice constant were 8.11-8.18Ao. FT-IR conform the results obtained by XRD. SEM conform the morphology of the samples and its grain size. Grain size decreased with increased of the concentration of Ca in Co0.6-x-Zn0.CaxFe2O4. TGA results were found in agreement with previous literatures
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