高度分散的化学性质相似的聚芴共聚物共混物中的调谐孔传输

M. J. Harding, R. Maher, L. Cohen, A. Campbell
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引用次数: 2

摘要

本文报道了不同比例的聚(9,9-二辛基芴-cobis- N,N'-(4-甲氧基苯基)-双-N,N'-苯基-1,4-苯二胺)(PFMO)和结构相似的聚(9,9-二辛基芴-co-N-(4-甲氧基苯基)二苯胺(TFMO)共混物的飞行时间(ToF)测量结果。结果表明,在10%的PFMO和90%的TFMO下,空穴迁移率可以调整3个数量级。我们还使用拉曼显微镜来证明混合物在我们实验的一微米分辨率内不会相分离。
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Tuning hole transport in a highly dispersed blend of chemically similar polyfluorene copolymers
Here we report results of time-of-flight (ToF) measurements on blends of different ratios of poly(9,9-dioctylfluorene-cobis- N,N'-(4-methoxylphenyl)-bis-N,N'-phenyl-1,4-phenylenediamine) (PFMO) and the structurally similar poly(9,9- dioctylfluorene-co-N-(4-methoxyphenyl)diphenylamine) (TFMO). It is shown that the hole mobility can be tuned over three orders of magnitude with a mobility minimum at 10% PFMO and 90% TFMO. We also use Raman microscopy to demonstrate that the blends do not phase separate within the one micron resolution of our experiment.
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