废塑料油-汽油混合物对火花点火发动机排放特性的影响

Gergő Kecsmár, T. Koós, Zsolt Dobó
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引用次数: 0

摘要

研究了不同塑料废物混合物热分解后的液体产物作为运输燃料的利用。在实验室规模的间歇式反应器中,利用聚苯乙烯(PS)、聚丙烯(PP)和高密度聚乙烯(HDPE)废物共混物生产热解油。两种不同的混合物(10% PS - 60% PP - 30% HDPE;制备了10% PS - 30% PP - 60% HDPE),并研究了回流的影响。热解油在0-100%范围内与商品汽油混合。研究发现,每种混合燃料都可以作为传统火花点火发动机的替代燃料,无需任何事先修改或燃料添加剂。然而,根据发动机测试,回流的存在是至关重要的,因为裂解油的成分更接近于商品汽油。排放测量显示,与纯汽油相比,氮氧化物排放量增加,但另一方面,一氧化碳排放量却有所减少。当在石油生产过程中使用回流时,这些变化要小得多。综上所述,利用回流冷却技术提高塑料废热解油中烃类的汽油范围是一种有效的方法,因此将这些油与商品汽油混合是可行的。
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Influence of WPO (Waste Plastic Oil) - gasoline mixtures for emission characteristics on working spark-ignition engine
The utilization of liquid products as transportation fuel derived from the thermal decomposition of different plastic waste mixtures was investigated. The production of pyrolysis oils was performed in a laboratory-scale batch reactor utilizing polystyrene (PS), polypropylene (PP), and high-density polyethylene (HDPE) waste blends. Two different mixtures (10% PS – 60% PP – 30% HDPE; 10% PS – 30% PP – 60% HDPE) were prepared, and the influence of reflux was also studied. The pyrolysis oils were blended to commercial gasoline in the 0-100% range. It was found that each blend could be successfully used as an alternative fuel in a traditional spark-ignition engine without any prior modifications or fuel additive. However, based on the engine tests, the presence of the reflux is vital as the composition of the pyrolysis oil is closer to the commercial gasoline. The emission measurements showed increasing NOx emissions compared to neat gasoline, but, on the other side, a decrease in CO was noticed. These changes were much smaller in cases when reflux was used during oil production. Based on the obtained results, the utilization of reflux-cooling is an effective method to enhance the gasoline range hydrocarbons in the plastic waste pyrolysis oils, and therefore blending these oils to commercial gasoline might be viable.
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