非中心氯化物的相互关系“结构-非线性光学性质”

V. Atuchin, B. Kidyarov
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引用次数: 0

摘要

结构参数和物理性质的表>100目前已知的简单和二元无中心氯晶体。通过与氟化物的比较,确定了晶体在点对称群上的分布。在晶格中化学键长度最短的金属-氯的平面上,出现了一簇非向心性椭圆。选择了一个化学键长度的组合,最有希望得到明显的非线性光学性质。
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Interrelationship “structure — Nonlinear optical properties” for acentric chlorides
Structural parameters and physical properties are tabulated for >100 presently known simple and binary acentric chloride crystals. Distribution of the crystals over point symmetry groups has been defined in comparison with that of fluorides. A rosette of ellipses of acentricity has been outlined on the plane of the shortest chemical bond lengths metal-chlorine in the crystal lattice. A combination of chemical bond lengths most promising for pronounced nonlinear optical properties has been selected.
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