磁场对镍钴纳米线电沉积的影响

Sidra Khalid, Zaheer Hussain Shah
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摘要

采用交流电沉积技术制备了阳极氧化氧化铝(AAO)纳米孔模板,并在平行于纳米线轴线方向的磁场存在和不存在的情况下,在AAO模板的纳米孔中合成了镍纳米线。钴(Co)纳米线是通过在纳米线轴线上施加垂直和平行方向的磁场制备的。磁场可以改变Ni和Co纳米线的晶粒优先生长。平行于纳米线轴线方向的磁场由于磁流体动力效应使沉积速率和电流密度增加,而垂直于电极表面方向的磁场对化学反应没有显著影响。在沉积过程中施加外加磁场也会影响材料的磁性能。这些变化与晶粒在Ni和Co纳米线优选方向上的生长有关。
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The Effect of Magnetic Field on Electro-deposition of Nickel and Cobalt Nanowires
Anodized Aluminum Oxide (AAO) nano-porous template is fabricated and nickel (Ni) nanowires are synthesized in the nano pores of AAO template by AC electro-deposition technique in the presence and absence of magnetic field applying only in a direction parallel to nanowire axis. Cobalt (Co) nanowires are fabricated by applying magnetic field externally both in perpendicular and parallel directions to the axis of nanowires. Magnetic field can bring change in the preferential grain growth of Ni and Co nanowires. Magnetic field applied parallel to nanowire axis increases deposition rate and current density due to magneto hydrodynamic effect, while magnetic field applied in perpendicular to the surface of electrode does not bring significant change in the chemical reaction. Magnetic properties are also affected by applying external magnetic field during deposition. These changes associated with grain growth in the preferred direction of Ni and Co nanowires are discussed in this article.
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