[6,6]-苯基- c61丁酸甲酯(PCBM)凝聚纳米结构对有机薄膜晶体管器件性能的影响

K. A. Mohamad, A. Alias, I. Saad, B. Gosh, K. Uesugi, H. Fukuda
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引用次数: 0

摘要

报道了[6,6]-苯基c61 -丁酸甲酯(PCBM)凝聚纳米结构对五苯基有机薄膜晶体管(OTFTs)器件性能的影响。在SiO2栅极介质上存在PCBM层,使得五苯基OTFTs具有较高的迁移率(μ = 0.95 ~ 2.2 cm2 V-1 s-1)、较低的阈值电压(Vth = -1.1 ~ -5.4 V)、较高的通断电流比(Ion/Ioff = 104)和较高的亚阈值斜率(SS = 6.5 V/decade)。表面形貌研究表明,PCBM纳米结构有利于晶界的减小,从而使五苯基otft具有更好的晶体管性能。PCBM对并五苯薄膜分子微观结构的影响为在otft上获得更高的性能提供了合理的解释。
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Effect of [6,6]-Phenyl-C61 butyric acid methyl ester (PCBM) agglomerated nanostructure on device performance in organic thin-film transistors
The influence of [6,6]-phenyl C61-butyric acid methyl ester (PCBM) agglomerated nanostructure on device performance of pentacene-based organic thin-film transistors (OTFTs) were reported. The presence of PCBM layers on a SiO2 gate dielectric resulted in a good electrical characteristics of pentacene-based OTFTs, including a relatively high mobility (μ = 0.95-2.2 cm2 V-1 s-1), low threshold voltages (Vth = -1.1 - -5.4 V), a high on/off current ratio (Ion/Ioff = 104), and a high value of subthreshold slope (SS = 6.5 V/decade). The surface topography studies reveal that the PCBM nanostructure could favor the reduction of grain boundaries, which resulted in a better transistor performance of pentacene-based OTFTs. The influence of PCBM on the molecular microstructure of pentacene thin films elucidates a reasonable explanation for higher performance on OTFTs.
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