对南非北开普省已修复和未修复的废弃石棉矿倾倒场附近人类住区捕获的粉尘和降尘样本进行研究

T. Mashalane, S. Moja, O. Novhe, M. Kwata, K. Masindi
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引用次数: 0

摘要

尽管南非已于2002年禁止石棉开采,但废弃的石棉矿坑继续对人类健康产生影响。石棉矿山排土场,特别是未修复的排土场,造成粉尘污染。来自这些矿坑的粉尘颗粒会进入附近的人类住区,造成健康风险。吸入悬浮在空气中的石棉纤维/粉尘会导致肺部疾病等呼吸系统健康问题。为了进行环境补救,选择了北开普省库鲁曼和普列斯卡周围已修复和未修复的地点,比较石棉的存在和修复的效果。测量和监测了从石棉矿排土场到最近人类住区半径5.0公里范围内的降尘量。对捕获的粉尘和降尘样品进行了表征。收集和测量降尘样本,使用2.0米的支架,并使用一个半满去离子水或蒸馏水的单开口桶。用胶带从室内和室外的相框、窗框、旧家具和屋顶上收集灰尘样本。采用x射线衍射(XRD)测定了室内和室外样品的矿物组成。矿物学和形态特征进一步验证了扫描电子显微镜与能量色散光谱(SEM-EDS)。XRD结果表明,角闪孔中含有大量的[Ca2(Fe,Mg)5Si8O22(OH)2]石棉矿物群。通过XRD检测到微量的蛇纹石[Mg3SiO5(OH)4]石棉矿物群,但SEM-EDS无法证实。然而,XRD和SEM-EDS结果均证实了角闪孔石棉矿物群的存在。其他检测到的硅酸盐矿物包括石英、滑石、云母、斜长石和长石。检测到的非硅酸盐矿物包括方解石、蒙脱石和微量赤铁矿。人类住区内接触石棉矿物仍然是一个主要的健康问题,样品特征证实了矿物的数量或水平和组成。
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A STUDY OF TRAPPED DUST AND DUSTFALL SAMPLES FROM HUMAN SETTLEMENTS NEAR REHABILITATED AND NON-REHABILITATED ABANDONED ASBESTOS MINE DUMPS IN THE NORTHERN CAPE PROVINCE, SOUTH AFRICA
Abandoned asbestos mine dumps continue to have an effect on human health notwithstanding the banning of asbestos mining in South Africa in 2002. Asbestos mine dumps, especially non-rehabilitated dumps, contribute to dust pollution. Dust particles from these mine dumps find their way to nearby human settlements and cause health risks. Respiratory health issues such as lung diseases are a result of inhaled asbestos fibres/dust suspended in the air. For the purpose of environmental remediation, rehabilitated and non-rehabilitated sites around Kuruman and Prieska in the Northern Cape Province were selected to compare the presence of asbestos and the effectiveness of rehabilitation. Dustfall within a radius of 5.0 km from the asbestos mine dump to the nearest human settlement was measured and monitored. Characterisation was done for both trapped dust and dustfall samples. Dustfall samples were collected and measured using a 2.0 m stand with a single open bucket half-filled with deionised or distilled water. Trapped dust samples were collected indoors and outdoors from photo frames, window frames, old furniture and roof tops using sticky tape. The mineralogical composition of both indoor and outdoor samples was determined by X-ray diffraction (XRD). Mineralogical and morphological characterisation was further validated using scanning electron microscopy with energy dispersive spectroscopy (SEM-EDS). The XRD results show significant amounts of the amphibole [Ca2(Fe,Mg)5Si8O22(OH)2] asbestos mineral group. Trace amounts of the serpentine [Mg3SiO5(OH)4] asbestos mineral group were detected by XRD but could not be confirmed by SEM-EDS. However, both XRD and SEM-EDS results confirmed the presence of the amphibole asbestos mineral group. Other silicate minerals detected include quartz, talc, mica, plagioclase and feldspar. Detected nonsilicate minerals include calcite, smectite and traces of haematite. Exposure of asbestos minerals within human settlements continues to be a major health concern and sample characterisation substantiates the amount or levels and composition of the minerals.
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