固态染料敏化太阳能电池用天然光敏剂

M. Tripathi, P. Chawla, Kamlesh Pandey
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引用次数: 1

摘要

天然染料敏化太阳能电池(DSSC)由于其结构简单、制造成本低等优点,作为新一代太阳能电池得到了广泛的研究。本研究将甜菜菁苷染料用于固体染料敏化太阳能电池的制备。甜菜菁苷染料是许多果实和叶子呈红色的染料,与太阳光谱具有良好的吸收光谱。以聚乙烯醇(PVA)、醋酸锂(Lithium acetate)、碳酸乙烯(Ethylene carbonate, EC)和碳酸丙烯(Propylene carbonate, PC)为材料,制备了一种纳米复合聚合物电解质,并以TiO2为填料,作为甜菜碱基染料敏化太阳能电池的固态薄膜电解质。将纳米复合聚合物与碘化铵络合,并在聚合物电解质中加入碘晶体。采用纳米复合聚合物电解质制备的DSSC具有良好的光伏性能,在AM 1.5下,短路光电流密度(Jsc)为9.8 mA cm-2,过载电压(Voc)为0.435 V,填充系数(ff)为52%,转换效率(η)为2.2%。
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Natural photosensitizers for solid-state dye sensitized solar cell
Natural dye sensitized solar cells (DSSC) have been widely investigated as a next generation solar cell because of their simple structure and low manufacturing cost. In the present work betacyanin dye responsible for the red color of many fruits and leaves having favorable absorption spectra with the solar spectrum has been used in fabrication of solid state dye sensitized solar cell. A Nanocomposite polymer electrolyte consisting of Poly vinyl alcohol (PVA), Lithium acetate, Ethylene carbonate (EC) and Propylene carbonate (PC) with TiO2 filler was used as a solid state thin film electrolyte for betacynin based Dye Sensitized Solar cell. The nanocomposite polymer was complexed with ammonium iodide and iodine crystals were added to the polymer electrolyte. The DSSC with the nanocomposite polymer electrolyte showed good photovoltaic performnance including short circuit photocurrent density (Jsc) 9.8 mA cm-2, the opencircuit volyage (Voc) 0.435 V, the fill factor (ff) of 52% and the conversion effeciency (η) of 2.2% under AM 1.5.
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