水处理技术使水泥窑粉尘在熟料生产中可重复利用

Zaki Mi
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摘要

水泥窑尘(CKD)是水泥熟料生产厂窑内煅烧过程中产生的副产物[1,2]。它是一种巨大的副产品(全世界每年约3000万吨,占水泥熟料产量的5- 20%[3-5]),通常是化学和颗粒大小的非均质混合物。这些特性取决于原料、燃料、窑炉热加工类型(干法或湿法)、总体设备布局和所生产的水泥种类[4,6]。但从化学上讲,它包括Ca、K、Na、Al、Fe和Si的氧化物、碳酸盐、氯化物和硫酸盐,其中CaO/CaCO3是其主要成分[2]。从熟料窑废气中分离出CKD是为了防止(i)熟料的碱含量超过最大允许值(≤0.6%)[7],以及(ii)生产的熟料中过量盐(氯化物和硫酸盐)的积累[7]。
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A Facil Water Treatment Rendering Cement Kiln Dust Reusable in Clinker Manufacturing
Cement kiln dust (denoted CKD) is by-produced during the calcination process in the kiln of cement clinker manufacturing plants [1,2]. It is a massive by-product (ca. 30 million tons/year worldwide and 5-20 % of the amount of cement clinker produced [3-5]) that is generally a heterogeneous mixture by chemistry and particulate size. These characteristics are dependent on the raw feed materials, fuels, kiln pyroprocessing type (dry or wet), overall equipment layout, and kind of cement being manufactured [4,6]. Chemically speaking, however, it includes oxides, carbonates, chlorides and sulfates of Ca, K, Na, Al, Fe and Si, with CaO/CaCO3 being its major constituent [2]. CKD is separated from the clinker kiln exhaust gas in order to prevent (i) the alkali content of the clinker from exceeding the maximum allowable value (≤0.6 %) [7], and (ii) the buildup of excessive salts (chlorides and sulfates) in the produced clinker [7].
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